2,6-Dimethyl-2-octyl acetate (CAS 68480-08-0) — Sweet Top Note Fragrance Ingredient

Sweet · Citrus

2,6-Dimethyl-2-octyl acetate

CAS 68480-08-0

Origin
synthetic
Note
Top
IFRA
Generally safe
Data as of: Apr 2026

What Is 2,6-Dimethyl-2-octyl acetate?

2,6-Dimethyl-2-octyl acetate is a synthetic fragrance ingredient used to create fresh, fruity, and slightly floral notes in perfumes and scented products. It is commonly found in air fresheners, detergents, and personal care items. This compound matters because it provides a long-lasting, pleasant aroma that enhances the overall scent profile without being overpowering.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for individual sensitivities
CAS
68480-08-0
Formula
Mixture
MW
Variable
Odor Family
Sweet · Citrus
Layer 1 · Enthusiast

What Does 2,6-Dimethyl-2-octyl acetate Smell Like?

2,6-Dimethyl-2-octyl acetate offers a crisp, fruity aroma with hints of pear and apple, layered over a subtle floral undertone. Its scent evolves from a bright, juicy top note to a smoother, slightly woody dry-down, making it versatile in fragrance compositions. The dry-down retains a clean, fresh character, ideal for modern, airy scents.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Fresh Splash(ScentCo, 2015)

Used to enhance the fruity top notes, providing a long-lasting fresh effect that blends seamlessly with citrus and floral elements.

Airy Breeze(AromaTech, 2018)

Adds a crisp, clean dimension to the fragrance, making it perfect for daytime and summer scents.

Layer 2

2D Molecular Structure

2-Octanol, 2,6-dimethyl-, 2-acetate

SMILES: CCC(C)CCCC(C)(C)OC(C)=O

Chemistry, Properties & Perfumer Guide

The Chemistry

2,6-Dimethyl-2-octyl acetate is an ester derived from the reaction of 2,6-dimethyl-2-octanol with acetic acid. It is a synthetic compound designed to mimic natural fruity and floral notes. Its molecular structure ensures stability and longevity in fragrance formulations.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Top
Volatility
Medium (60-120 min)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance2-5%Up to 10%Adds fruity freshness
Household Products1-3%Up to 5%Provides clean scent

Classic Accords

Tip: Use in moderation to avoid overpowering other notes.

Alternatives & Comparisons

1
Isoamyl acetate CAS 123-92-2

Offers a similar fruity note but with a shorter lifespan.

2
Hexyl acetate CAS 142-92-7

Provides a greener, more natural fruity aroma.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under current IFRA standards.

RIFM Assessment

Currently under review by RIFM for comprehensive safety assessment.

Sustainability

As a synthetic compound, 2,6-Dimethyl-2-octyl acetate is produced in controlled environments, minimizing environmental impact. Its production does not rely on natural resources, making it a sustainable choice for large-scale fragrance applications.

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References

  1. PubChem: 2,6-Dimethyl-2-octyl acetate PubChem
  2. IFRA Standards Library IFRA

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

Report a data error

Physicochemical Properties

DTXSID: DTXSID70867642

Physical Properties

Molecular Weight 200.322 g/mol🔬 EPA CompTox
Density 0.856 g/cm^3📊 OPERA
Boiling Point 221.783 °C📊 OPERA
Melting Point -37.281 °C📊 OPERA
Flash Point 81.737 °C📊 OPERA
Refractive Index 1.428 Dimensionless📊 OPERA
Molar Volume 230.524 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 4.668 Log10 unitless📊 OPERA
LogD (pH 5.5) 4.668 Log10 unitless📊 OPERA
LogD (pH 7.4) 4.668 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 5.78 Log10 unitless📊 OPERA
Water Solubility 0 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.13 mmHg📊 OPERA
Viscosity 2.029 cP📊 OPERA
Surface Tension 26.288 dyn/cm📊 OPERA
Thermal Conductivity 126.676 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 26.3 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 2 count💻 Computed
Rotatable Bonds 6 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 59.342 cm^3/mol📊 OPERA
Polarizability 23.525 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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