2-Bornyl propionate (CAS 20279-25-8) — Woody Middle Note Fragrance Ingredient
2-Bornyl propionate
CAS 20279-25-8
What Is 2-Bornyl propionate?
2-Bornyl propionate is a synthetic fragrance ingredient occasionally found in pine-scented household cleaners and masculine colognes. It contributes a crisp, woody-pine character with subtle fruity undertones. This molecule matters because it mimics natural pine aromas without relying on pine tree harvesting, offering a sustainable alternative for forest-inspired scents.
Safety Profile
GENERALLY SAFEWhat Does 2-Bornyl propionate Smell Like?
2-Bornyl propionate opens with a brisk pine needle sharpness reminiscent of alpine forests after rain, quickly revealing a hidden fruity dimension like unripe pineapple skin. The heart develops a clean woody character with camphoraceous undertones, while the dry-down leaves a subtle balsamic warmth. Unlike raw pine oils, it lacks resinous stickiness, presenting instead as a polished, almost metallic interpretation of coniferous aromas.
2D Molecular Structure
SMILES: CCC(=O)OC1CC2CCC1(C)C2(C)C
Chemistry, Properties & Perfumer Guide
The Chemistry
2-Bornyl propionate is an ester formed by the reaction of borneol with propionic acid. As a synthetic terpenoid, it belongs to the bicyclic monoterpene class. Industrial synthesis typically involves esterification of commercially available borneol under acidic conditions. The molecule exhibits chirality, with the (1R)-enantiomer being more common in fragrance applications due to its cleaner olfactory profile compared to the racemic mixture.
Physical & Chemical Properties
| Boiling Point | Not available |
|---|---|
| Density | Not available |
Perfumer Guide
| Application | Typical % | Range | Notes |
|---|---|---|---|
| Fine Fragrance | 0.5-2% | Up to 5% | Pine accord modifier |
| Household Cleaners | 1-3% | Up to 8% | Disinfectant-type freshness |
Classic Accords
Tip: Use to add crispness to synthetic pine accords without introducing the stickiness of natural pine resins.
Alternatives & Comparisons
More camphoraceous pine note with higher volatility, suitable for top notes in similar applications.
Natural counterpart with softer, rounder pine character but lower stability in formulations.
Safety, Regulatory & Sustainability
⚠ Regulatory Disclaimer
General reference only. Consult current IFRA Standards Library before formulating.
IFRA Status
Not restricted under current IFRA standards (Amendment 49).
RIFM Assessment
No RIFM safety assessment currently available.
Sustainability
As a fully synthetic material, 2-Bornyl propionate reduces pressure on natural pine resources. Production typically uses petrochemical feedstocks, though bio-based routes from turpentine derivatives are theoretically possible. The material’s stability reduces waste in formulations compared to natural pine extracts.
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Physicochemical Properties
DTXSID: DTXSID70859764
Physical Properties
| Molecular Weight | 210.317 g/mol🔬 EPA CompTox |
| Density | 0.96 g/cm^3📊 OPERA |
| Boiling Point | 230.543 °C📊 OPERA |
| Melting Point | 52.95 °C📊 OPERA |
| Flash Point | 94.187 °C📊 OPERA |
Partition & Solubility
| LogP (Octanol-Water) | 3.154 dimensionless💻 Computed |
| Water Solubility | 0.002 mol/L📊 OPERA |
Transport Properties
| Vapor Pressure | 0.044 mmHg📊 OPERA |
| Viscosity | 9.15 cP📊 OPERA |
| Surface Tension | 30.365 dyn/cm📊 OPERA |
| Thermal Conductivity | 115.809 mW/(m*K)📊 OPERA |
Molecular Descriptors
| Topological Polar Surface Area | 26.3 Ų💻 Computed |
| H-Bond Donors | 0 count💻 Computed |
| H-Bond Acceptors | 2 count💻 Computed |
| Rotatable Bonds | 2 count💻 Computed |
| Aromatic Rings | 0 count💻 Computed |
Data Sources:
🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.
