8-Nonenal (CAS 39770-04-02) — Green Top Note Fragrance Ingredient

Green · Sweet

8-Nonenal

CAS 39770-04-02

Origin
synthetic
Note
Top
IFRA
Use with awareness
Data as of: Apr 2026

What Is 8-Nonenal?

8-Nonenal is a synthetic fragrance ingredient that creates a distinctive cucumber-like aroma with fatty undertones. It’s often used in fine fragrances and personal care products to add fresh, green nuances. This aldehyde is valued by perfumers for its ability to impart crisp, watery freshness reminiscent of sliced cucumbers or melons, making it popular in aquatic and fresh fragrance compositions.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
Approved for fragrance use
Potential skin sensitizer at high concentrations
CAS
39770-04-02
Formula
Mixture
MW
Variable
Odor Family
Green · Sweet
Layer 1 · Enthusiast

What Does 8-Nonenal Smell Like?

8-Nonenal bursts with an intensely fresh, cucumber-watermelon rind character that’s both cooling and slightly fatty. The initial impression is like slicing into a ripe honeydew melon, with a waxy greenness that evolves into a more vegetal, almost squash-like heart. As it dries down, it reveals subtle marine undertones reminiscent of ocean air, making it invaluable for aquatic accords. The fatty aspect lingers as a skin-like note, creating surprising depth for such a fresh-smelling molecule.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

L'Eau d'Issey(Issey Miyake, 1992)

Used to create the signature watery melon effect that defines this aquatic classic, blending with calone for a dewy freshness.

Cool Water(Davidoff, 1988)

Contributes to the cucumber-like freshness in the top notes, enhancing the marine accord with its green, watery character.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

8-Nonenal is a C9 aldehyde with a terminal double bond, belonging to the class of α,β-unsaturated aldehydes. Synthesized through ozonolysis of cyclooctene followed by reductive workup, or via hydroformylation of 1,7-octadiene. The E-isomer predominates in commercial samples due to greater stability. Its reactivity comes from both the aldehyde group and alkene functionality, requiring stabilization with antioxidants in fragrance applications. The molecule’s volatility and polarity make it effective at creating immediate fresh top notes.

Physical & Chemical Properties

Boiling Point~185 °C (estimated)
Density~0.85 g/cm³ (estimated)

Perfumer Guide

Note Position
Top
Volatility
High (30-90 min)
Blending
Good with citrus and marine notes
ApplicationTypical %RangeNotes
Fine Fragrance0.1-0.5%Up to 1%Fresh top note in aquatic compositions
Shower Gels0.01-0.1%Up to 0.2%Enhances clean, fresh character

Classic Accords

Tip: Stabilize with 0.1% BHT to prevent oxidation during storage.

Alternatives & Comparisons

1
2,6-Nonadienal CAS 557-48-2

More intense cucumber character but less stable; use when a stronger vegetable effect is desired.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No specific IFRA restrictions. General aldehyde precautions apply.

GHS Classification

H315 Skin irritation H317 May cause allergic skin reaction

RIFM Assessment

RIFM assessment complete; safe at current use levels.

Sustainability

Synthesized from petrochemical feedstocks via efficient catalytic processes. No known ecological concerns at current production volumes. Being synthetic, it doesn’t impact agricultural land use but depends on non-renewable resources.

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References

  1. Bauer et al. (2001). Common Fragrance and Flavor Materials. Wiley-VCH.

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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