Amyl hexanoate (CAS 0540-07-08) — Sweet Top Note Fragrance Ingredient

Sweet · Citrus

Amyl hexanoate

CAS 0540-07-08

Origin
synthetic
Note
Top
IFRA
Generally safe
Data as of: Apr 2026

What Is Amyl hexanoate?

Amyl hexanoate is a synthetic fragrance compound that smells like ripe, tropical fruits. You’ll encounter it in fruity perfumes, flavored foods, and some household products. This ester adds a juicy, banana-like sweetness that makes scents feel more natural and appetizing.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
No major safety concerns
Use standard ester precautions
CAS
0540-07-08
Formula
Mixture
MW
Variable
Odor Family
Sweet · Citrus
Layer 1 · Enthusiast

What Does Amyl hexanoate Smell Like?

Amyl hexanoate bursts with a bright, banana-like sweetness reminiscent of tropical fruit cocktails. The initial impression is juicy and slightly green, like peeling a just-ripe banana. As it evolves, it reveals subtle pear and pineapple nuances with a creamy undertone. The dry-down retains a soft fruity character but becomes more diffuse, blending seamlessly with floral and woody notes. Its volatility makes it perfect for creating naturalistic top notes that don’t overpower.

Scent Profile
Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Amyl hexanoate is an ester formed by the condensation of hexanoic acid and amyl alcohol. Industrially produced via acid-catalyzed esterification, it’s a staple in flavor and fragrance chemistry. The molecule lacks chiral centers, making synthesis straightforward. Its relatively small size contributes to high volatility and intense fruity odor.

Physical & Chemical Properties

Perfumer Guide

Note Position
Top
Volatility
High (30-90 min)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-3%Up to 5%Fruity top note accent
Functional Fragrance0.5-2%Up to 3%Adds fruity freshness

Classic Accords

Tip: Use to boost natural fruit effects without overwhelming floral heart notes.

Alternatives & Comparisons

1
Isoamyl acetate CAS 123-92-2

More banana-forward with sharper top notes. Better for candy-like compositions.

2
Hexyl acetate CAS 142-92-7

Softer pear-like character with longer persistence.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not restricted under current IFRA standards.

RIFM Assessment

Considered safe at current usage levels based on RIFM evaluation.

Sustainability

As a synthetic material, amyl hexanoate has minimal environmental impact from sourcing. Production typically uses petrochemical feedstocks, but green chemistry routes using bio-based alcohols are being developed. Biodegradability is excellent due to ester functionality.

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References

    Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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