Benzyl acetone (CAS 2550-26-7) — Floral Middle Note Fragrance Ingredient

Floral · Sweet

Benzyl acetone

CAS 2550-26-7

Origin
synthetic
Note
Middle
IFRA
Generally safe
Data as of: Apr 2026

What Is Benzyl acetone?

Benzyl acetone is a synthetic fragrance ingredient with a sweet, floral, and slightly fruity aroma. It is commonly used in perfumes, soaps, and detergents. This ingredient is valued for its ability to enhance floral compositions and add a touch of sweetness to various fragrance formulations.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for potential allergens
CAS
2550-26-7
Formula
Mixture
MW
Variable
Odor Family
Floral · Sweet
Layer 1 · Enthusiast

What Does Benzyl acetone Smell Like?

Benzyl acetone offers a sweet, floral scent reminiscent of jasmine and lilac, with subtle fruity undertones. It evolves from a bright top note to a soft, powdery heart, settling into a gentle, lingering sweetness. Its dry-down is smooth and slightly woody, making it a versatile middle note in floral and fruity accords.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Chanel No. 5(Chanel, 1921)

Used to enhance the floral bouquet, adding a sweet, powdery dimension to the iconic jasmine and rose heart.

Dior J'adore(Dior, 1999)

Contributes to the radiant floralcy, blending seamlessly with ylang-ylang and Damascus rose.

Layer 2

2D Molecular Structure

Benzylacetone

SMILES: CC(=O)CCC1=CC=CC=C1

Chemistry, Properties & Perfumer Guide

The Chemistry

Benzyl acetone is a simple aromatic ketone, synthesized via the condensation of benzaldehyde with acetone. It belongs to the phenylpropanoid class of compounds, often used as a precursor in the synthesis of more complex fragrance molecules. Its straightforward structure makes it a versatile building block in perfumery.

Physical & Chemical Properties

Boiling Point235 °C
Density1.001 g/cm³

Perfumer Guide

Note Position
Middle
Volatility
Medium (2-4 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance2-5%Up to 10%Floral enhancer
Soaps1-3%Up to 5%Sweetness booster

Classic Accords

+ Jasmine + Vanilla = Floral Gourmand + Rose + Sandalwood = Powdery Woody

Tip: Use in floral compositions to add sweetness and depth.

Alternatives & Comparisons

1
Benzyl Alcohol CAS 100-51-6

A milder alternative with similar floral notes but less sweetness.

2
Phenethyl Alcohol CAS 60-12-8

Offers a rosier profile with comparable floral sweetness.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not restricted by IFRA.

RIFM Assessment

RIFM has assessed benzyl acetone as safe for use in current applications.

Sustainability

Benzyl acetone is synthetically produced, reducing reliance on natural resources. Its production is efficient, with minimal environmental impact when handled responsibly.

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References

  1. PubChem. Benzyl Acetone. PubChem CID: 7524

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID6033241

Physical Properties

Molecular Weight 148.205 g/mol🔬 EPA CompTox
Density 0.987 g/cm^3🔬 EPA CTX
Boiling Point 235.65 °C🔬 EPA CTX
Melting Point -13.65 °C🔬 EPA CTX
Flash Point 99.05 °C🔬 EPA CTX
Refractive Index 1.504 Dimensionless📊 OPERA
Molar Volume 152.384 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 2 Log10 unitless🔬 EPA CTX
LogD (pH 5.5) 2.153 Log10 unitless📊 OPERA
LogD (pH 7.4) 2.153 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 5.26 Log10 unitless📊 OPERA
Water Solubility 0.019 mol/L🔬 EPA CTX
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.047 mmHg🔬 EPA CTX
Viscosity 2.501 cP📊 OPERA
Surface Tension 34.963 dyn/cm📊 OPERA
Thermal Conductivity 143.112 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 17.07 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 3 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 45.097 cm^3/mol📊 OPERA
Polarizability 17.878 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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