Lime oil, terpeneless (CAS 68916-84-7) — Citrus Top to Middle Note Fragrance Ingredient
Lime oil, terpeneless
CAS 68916-84-7
What Is Lime oil, terpeneless?
Terpeneless lime oil is a concentrated version of regular lime essential oil, with the terpenes removed for a more intense and longer-lasting citrus character. You’ll find it in high-end citrus fragrances, gourmand perfumes, and some artisanal cleaning products. This processed oil matters because it delivers the bright, zesty punch of lime without the volatility and ‘cleaning product’ associations of standard lime oil, making it a perfumer’s secret weapon for sophisticated citrus accords.
Safety Profile
GENERALLY SAFEWhat Does Lime oil, terpeneless Smell Like?
Terpeneless lime oil bursts with a hyper-realistic, almost candied lime peel intensity – think key lime pie filling without the sweetness. The opening is a laser-focused citrus zing, cleaner than regular lime oil with none of the turpentine-like terpene sharpness. As it evolves, a surprisingly creamy undertone emerges, like the white pith of fresh lime. The dry-down reveals subtle green nuances and a whisper of tartness that lingers far longer than standard citrus oils, behaving more like a heart note than a fleeting top note.
In Famous Fragrances
Fragrance associations may not reflect actual formulations.
Uses terpeneless lime as the sparkling backbone of this cologne, where its extended longevity allows the citrus to dance with mint and herbal notes rather than disappearing immediately.
The terpeneless lime here provides a crisp contrast to sweet almond, creating a sophisticated ‘limoncello’ effect that persists through the creamy dry-down.
Chemistry, Properties & Perfumer Guide
The Chemistry
Terpeneless lime oil is produced by vacuum distillation or solvent extraction of cold-pressed lime oil (Citrus aurantifolia), selectively removing volatile monoterpenes like limonene and pinene. This concentrates oxygenated compounds such as citral, geraniol, and linalool. The process increases the relative percentage of sesquiterpenes and non-volatile components, dramatically altering the odor profile and stability. Unlike most citrus oils which are dominated by limonene (up to 70%), terpeneless versions may contain less than 10% terpenes, with the remaining composition being primarily alcohols, aldehydes, and esters responsible for the characteristic lime aroma.
Physical & Chemical Properties
| Appearance | Pale yellow to greenish liquid |
|---|---|
| Solubility | Soluble in alcohol, insoluble in water |
Perfumer Guide
| Application | Typical % | Range | Notes |
|---|---|---|---|
| Fine Fragrance | 1-3% | Up to 5% | Adds bright citrus lift without harshness |
| Functional Fragrances | 0.5-2% | Up to 3% | Clean citrus character in detergents |
Classic Accords
Tip: Use as a bridge between classic citrus top notes and floral heart notes, where its persistence creates seamless transitions.
Alternatives & Comparisons
For more traditional citrus profiles with higher volatility and terpenic character, though requires more careful blending to avoid household cleaner associations.
When a pure lemon-lime aldehyde character is needed, but lacks the natural complexity and roundness of terpeneless lime oil.
Safety, Regulatory & Sustainability
⚠ Regulatory Disclaimer
General reference only. Consult current IFRA Standards Library before formulating.
IFRA Status
No restrictions under IFRA 51st Amendment. The terpene removal process reduces phototoxic concerns associated with cold-pressed lime oil.
EU Allergen Declaration
May contain trace amounts of limonene (requires labeling above 0.001% in leave-on products).
RIFM Assessment
RIFM evaluation confirms safety at current use levels, with phototoxicity concerns significantly reduced compared to whole lime oil.
Sustainability
Terpeneless lime oil represents an efficient use of citrus resources, as the removed terpenes (mainly limonene) are valuable byproducts used in industrial applications. The concentration process means less raw material is needed per unit of fragrance impact. Most production originates from Mexico and Brazil, where lime cultivation is well-established, though synthetic alternatives exist for consistent supply.
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Ingredient Data Sheet
CAS 68916-84-7Odor & Flavor
| Terpeneless oil is prepared from distilled lime oil by the conventional method of deterpenation. The terpeneless fraction constitutes a very small fraction of the lime oil. It has a powerful, sweet-fruity, grape-like odor. -📖 Fenaroli |
Regulatory Status
| IOFI Classification | Natural📖 Fenaroli |
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.
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