Methyl furfuryl disulfide (CAS 57500-00-2) — Sweet Heart to base Note Fragrance Ingredient

Sweet · Balsamic

Methyl furfuryl disulfide

CAS 57500-00-2

Origin
synthetic
Note
Heart to base
IFRA
Use with awareness
Data as of: Apr 2026

What Is Methyl furfuryl disulfide?

Methyl furfuryl disulfide is a synthetic sulfur compound used in fragrance formulations. It’s found in trace amounts in roasted coffee and cooked meats, but perfumers use the pure synthetic version. This molecule matters because it adds savory, roasted nuances to fragrances, creating depth in gourmand and coffee accords.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
IFRA-approved at low levels
Strong odor – use sparingly
CAS
57500-00-2
Formula
Mixture
MW
Variable
Odor Family
Sweet · Balsamic
Layer 1 · Enthusiast

What Does Methyl furfuryl disulfide Smell Like?

Methyl furfuryl disulfide delivers an intense, roasted coffee bean character with sulfury undertones reminiscent of freshly brewed espresso. The top note bursts with dark, almost burnt caramel aspects that evolve into a heart of savory meatiness. In dry-down, it leaves a lingering roasted nut quality. Used at minute concentrations, it adds incredible depth to gourmand compositions, behaving like culinary MSG for perfumery – amplifying surrounding sweet and roasted notes.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Black Afgano(Nasomatto, 2009)

Used here to amplify the dark coffee and cannabis accord, adding a roasted edge that makes the fragrance smell almost edible yet mysterious.

Intense Café(Montale, 2014)

Provides the authentic roasted coffee bean character that forms the core of this sweet gourmand, blending seamlessly with vanilla and rose.

Layer 2

2D Molecular Structure

Furan, 2-[(methyldithio)methyl]-

SMILES: CSSCC1=CC=CO1

Chemistry, Properties & Perfumer Guide

The Chemistry

Methyl furfuryl disulfide belongs to the organosulfur compound class, specifically a disulfide derivative of furan. While occurring naturally in trace amounts during Maillard reactions (coffee roasting, meat cooking), perfumery uses synthetically produced material for consistency. Synthesis typically involves reacting furfuryl mercaptan with methyl disulfide in controlled conditions. The molecule’s potency comes from its sulfur-furan combination, creating strong odor characteristics at extremely low thresholds.

Physical & Chemical Properties

AppearanceColorless to pale yellow liquid
Odor ThresholdExtremely low (ppb range)

Perfumer Guide

Note Position
Heart to base
Volatility
Moderate (hours)
Blending
Specialist
ApplicationTypical %RangeNotes
Fine Fragrance0.01-0.1%Up to 0.5%Extremely powerful – overdose causes sulfurous off-notes

Classic Accords

Tip: Always pre-dilute to 1% or lower before incorporating into blends due to extreme potency.

Alternatives & Comparisons

1
Furfuryl mercaptan CAS 98-02-2

More coffee-forward without the sulfury depth, useful when a cleaner roasted note is desired.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No specific restrictions under current IFRA standards (as of 48th Amendment).

RIFM Assessment

RIFM has evaluated related furan derivatives but no specific assessment found for this compound.

Sustainability

As a synthetic material, production avoids agricultural impacts but requires controlled chemical synthesis. The extreme potency means minimal quantities are needed per formulation, reducing overall environmental load compared to less potent materials.

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References

  1. Burdock, G.A. (2010). Fenaroli’s Handbook of Flavor Ingredients. CRC Press.

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 57500-00-2

Physical Properties

Molecular Weight160.3 g/mol🔬 PubChem
LogP (Octanol-Water)1.5🔬 PubChem
Boiling Point64 °C🔬 EPA CompTox
log Kp (skin permeability)-2.613💻 Calculated
SMILESCSSCC1=CC=CO1🔬 PubChem

Volatility & Performance

Fragrance NoteTop💻 Calculated

Odor & Flavor

Primary Descriptorsonionroasted• leffingwell
Functional Groupsaromatic💻 RDKit
Methyl furfuryl disulfide has a berry, fruity, vegetable flavor. -📖 Fenaroli

Sensory Thresholds

Odor Detection Threshold0.1523 ppm (n=4)📖 van Gemert

Regulatory Status

IOFI ClassificationNature Identical📖 Fenaroli
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID9069186

Physical Properties

Molecular Weight 160.25 g/mol🔬 EPA CompTox
Density 1.181 g/cm^3🔬 EPA CTX
Boiling Point 218.389 °C📊 OPERA
Melting Point 16.448 °C📊 OPERA
Flash Point 84.495 °C📊 OPERA
Refractive Index 1.577 Dimensionless📊 OPERA
Molar Volume 132.984 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 3.254 Log10 unitless📊 OPERA
LogD (pH 5.5) 3.254 Log10 unitless📊 OPERA
LogD (pH 7.4) 3.254 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 5.28 Log10 unitless📊 OPERA
Water Solubility 0.014 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.059 mmHg📊 OPERA
Surface Tension 40.046 dyn/cm📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 13.14 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 3 count💻 Computed
Rotatable Bonds 3 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 44.096 cm^3/mol📊 OPERA
Polarizability 17.481 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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