1-Methyl-4-(isopropyl)cyclohexan-1-ol (CAS 21129-27-1) — Woody Middle Note Fragrance Ingredient

Woody · Green

1-Methyl-4-(isopropyl)cyclohexan-1-ol

CAS 21129-27-1

Origin
synthetic
Note
Middle
IFRA
Generally safe
Data as of: Apr 2026

What Is 1-Methyl-4-(isopropyl)cyclohexan-1-ol?

1-Methyl-4-(isopropyl)cyclohexan-1-ol is a synthetic fragrance ingredient used in perfumes and personal care products. It contributes to fresh, woody, and slightly herbal scent profiles. This molecule is valued for its stability and versatility in modern fragrance compositions.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for individual sensitivity
CAS
21129-27-1
Formula
Mixture
MW
Variable
Odor Family
Woody · Green
Layer 1 · Enthusiast

What Does 1-Methyl-4-(isopropyl)cyclohexan-1-ol Smell Like?

1-Methyl-4-(isopropyl)cyclohexan-1-ol offers a crisp, woody aroma with subtle herbal undertones. The scent evolves from a fresh, slightly camphoraceous opening to a clean, dry woody heart. Its dry-down is smooth and persistent, blending well with other woody and citrus notes. The overall impression is reminiscent of freshly cut wood with a hint of minty coolness.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Wood Sage & Sea Salt(Jo Malone, 2014)

Used to enhance the woody, earthy facets of this fragrance, providing a clean and natural woodiness that complements the sage and sea salt notes.

Terre d'Hermès(Hermès, 2006)

Adds a crisp, woody dimension to the citrus and mineral notes, contributing to the fragrance’s modern, earthy character.

Santal 33(Le Labo, 2011)

Used to amplify the woody and slightly smoky aspects, blending seamlessly with the sandalwood and cedar notes.

Bleu de Chanel(Chanel, 2010)

Provides a fresh, woody backbone that supports the citrus and incense notes, adding depth and longevity.

Aventus(Creed, 2010)

Contributes to the woody, smoky facets of this iconic fragrance, enhancing its masculine and sophisticated profile.

Layer 2

2D Molecular Structure

Cyclohexanol, 1-methyl-4-(1-methylethyl)-

SMILES: CC(C)C1CCC(C)(O)CC1

Chemistry, Properties & Perfumer Guide

The Chemistry

1-Methyl-4-(isopropyl)cyclohexan-1-ol is a synthetic terpene alcohol with a cyclohexane backbone. It is typically synthesized via hydrogenation of corresponding terpenes or through catalytic processes. The molecule’s structure allows for good stability and moderate volatility, making it suitable for various fragrance applications. Its isopropyl group contributes to its woody character, while the hydroxyl group enhances its solubility in common fragrance solvents.

Physical & Chemical Properties

Boiling PointNot available
DensityNot available

Perfumer Guide

Note Position
Middle
Volatility
Moderate (2-4 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance2-5%Up to 10%Adds woody depth
Personal Care1-3%Up to 5%Provides fresh woody notes
Household Products0.5-2%Up to 3%Enhances clean, woody scents

Classic Accords

Tip: Use in woody accords to add freshness and lift without overpowering other notes.

Alternatives & Comparisons

1
Cedrol CAS 77-53-2

A natural alternative with similar woody characteristics but less freshness.

2
Vertofix CAS 68039-49-6

Offers a more pronounced woody-ambery profile with better tenacity.

3
Iso E Super CAS 54464-57-2

Provides a smoother, more diffusive woody note with less herbal character.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not restricted by IFRA.

RIFM Assessment

No specific safety concerns identified by RIFM.

Sustainability

As a synthetic ingredient, 1-Methyl-4-(isopropyl)cyclohexan-1-ol is produced through controlled chemical processes, reducing the environmental impact associated with natural extraction. Its synthesis can be optimized for minimal waste and energy use, making it a sustainable choice for modern fragrance formulations.

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References

  1. PubChem Compound Summary for 1-Methyl-4-(isopropyl)cyclohexan-1-ol PubChem
  2. IFRA Standards Library IFRA
  3. RIFM Fragrance Ingredient Safety Assessment RIFM

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 21129-27-1

Physical Properties

Molecular Weight156.26 g/mol🔬 PubChem
LogP (Octanol-Water)2.6🔬 PubChem
Boiling Point208.5 °C🔬 EPA CompTox
Vapor Pressure0.0316 mmHg @ 25°C📊 OPERA
Flash Point83.4 °C🔬 EPA CompTox
Involatility Index0.0027💻 Calculated
log Kp (skin permeability)-1.807💻 Calculated
SMILESCC(C)C1CCC(CC1)(C)O🔬 PubChem

Volatility & Performance

Fragrance NoteHeart💻 Calculated
Volatility ClassVery slow💻 Calculated
Persistence Score2.5 / 5💻 Calculated

Odor & Flavor

Primary Descriptorsgreenwoody• leffingwell
Functional Groupsalcohol💻 RDKit
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID3066681

Physical Properties

Molecular Weight 156.269 g/mol🔬 EPA CompTox
Density 0.898 g/cm^3📊 OPERA
Boiling Point 208.5 °C🔬 EPA CTX
Melting Point 59.176 °C📊 OPERA
Flash Point 84.79 °C📊 OPERA
Refractive Index 1.461 Dimensionless📊 OPERA
Molar Volume 173.973 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 3.192 Log10 unitless📊 OPERA
LogD (pH 5.5) 3.192 Log10 unitless📊 OPERA
LogD (pH 7.4) 3.192 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 6.71 Log10 unitless📊 OPERA
Water Solubility 0.005 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.039 mmHg📊 OPERA
Viscosity 8.686 cP📊 OPERA
Surface Tension 30.5 dyn/cm📊 OPERA
Thermal Conductivity 128.137 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 20.23 Ų💻 Computed
H-Bond Donors 1 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 1 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 47.739 cm^3/mol📊 OPERA
Polarizability 18.925 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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