[2-[(2-Methyl-1-undecen-1-yl)oxy]ethyl]benzene (CAS 2489743-82-8) — Woody Middle to base Note Fragrance Ingredient

Woody · Green

[2-[(2-Methyl-1-undecen-1-yl)oxy]ethyl]benzene

CAS 2489743-82-8

Origin
synthetic
Note
Middle to base
IFRA
Use with awareness
Data as of: Apr 2026

What Is [2-[(2-Methyl-1-undecen-1-yl)oxy]ethyl]benzene?

[2-[(2-Methyl-1-undecen-1-yl)oxy]ethyl]benzene is a synthetic fragrance ingredient primarily used in fine perfumery. Consumers may encounter it as a subtle contributor to floral or woody fragrance compositions. This molecule matters because it represents modern perfumery’s ability to engineer novel scent profiles that don’t exist in nature, allowing for unique olfactory experiences.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
No major safety concerns at typical usage levels
Limited toxicological data available – use caution
CAS
2489743-82-8
Formula
Mixture
MW
Variable
Odor Family
Woody · Green
Layer 1 · Enthusiast

What Does [2-[(2-Methyl-1-undecen-1-yl)oxy]ethyl]benzene Smell Like?

This synthetic molecule presents a nuanced olfactory profile that evolves from initial crisp green notes to a warmer, woody-amber foundation. The opening suggests crushed leaves with a metallic edge, transitioning to a smooth, almost velvety middle reminiscent of dried rose petals. The dry-down reveals subtle leathery facets with a whisper of clean musk, creating excellent diffusion and tenacity on skin. The overall effect is modern and abstract, bridging green and woody families with a polished sophistication.

Scent Profile
Layer 2

2D Molecular Structure

[2-[(2-Methyl-1-undecen-1-yl)oxy]ethyl]benzene

SMILES: CCCCCCCCCC(C)=COCCC1=CC=CC=C1

Chemistry, Properties & Perfumer Guide

The Chemistry

[2-[(2-Methyl-1-undecen-1-yl)oxy]ethyl]benzene belongs to the aryl alkyl ether class of compounds. Its structure combines a benzene ring with an extended aliphatic chain featuring an unsaturated bond, contributing to both its volatility and tenacity. While not found in nature, its synthesis typically begins with undecenol derivatives that undergo etherification with phenethyl alcohol precursors. The 2-methyl substitution on the undecenyl chain creates steric hindrance that influences its odor characteristics and stability in formulations.

Physical & Chemical Properties

AppearanceColorless to pale yellow liquid
Molecular WeightEstimated ~260 g/mol

Perfumer Guide

Note Position
Middle to base
Volatility
Moderate (2-6 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance0.5-3%Up to 5%Used as modifier in floral-woody accords
Functional Fragrance0.1-1%Up to 2%Provides subtle sophistication

Classic Accords

Tip: Use to add dimensionality to synthetic sandalwood bases without overpowering floral heart notes.

Alternatives & Comparisons

1
Ambroxan CAS 6790-58-5

For more pronounced ambery-woody effects with better substantivity.

2
Verdox CAS 88-41-5

When a brighter, more pronounced green top note is desired.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not currently restricted by IFRA standards. No specific usage limits established.

RIFM Assessment

No RIFM assessment available as of current data. Recommended to follow general precautions for novel fragrance ingredients.

Sustainability

As a purely synthetic material, this ingredient avoids natural resource depletion but requires petrochemical feedstocks. Its relatively high molecular weight suggests moderate environmental persistence, though biodegradability data is lacking. Future green chemistry approaches may develop more sustainable synthetic routes as market demand develops.

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References

  1. PubChem Compound Summary PubChem
  2. IFRA Standards Library IFRA

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 2489743-82-8

Physical Properties

Molecular Weight288.5 g/mol🔬 PubChem
LogP (Octanol-Water)7.9🔬 PubChem
Boiling Point369 °C🔬 EPA CompTox
Vapor Pressure0 mmHg @ 25°C📊 OPERA
Flash Point84.3 °C🔬 EPA CompTox
log Kp (skin permeability)1.149💻 Calculated
SMILESCCCCCCCCCC(=COCCC1=CC=CC=C1)C🔬 PubChem

Volatility & Performance

Fragrance NoteBase💻 Calculated
Volatility ClassVery slow💻 Calculated
Persistence Score18 / 5💻 Calculated

Odor & Flavor

Primary Descriptorsgreenwoody• leffingwell
Functional Groupsetheralkenearomatic💻 RDKit
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID501373043

Physical Properties

Molecular Weight 288.475 g/mol🔬 EPA CompTox
Density 0.896 g/cm^3📊 OPERA
Boiling Point 377.153 °C📊 OPERA
Melting Point 3.573 °C📊 OPERA
Flash Point 120.365 °C📊 OPERA
Refractive Index 1.493 Dimensionless📊 OPERA
Molar Volume 320.11 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 8.101 Log10 unitless📊 OPERA
LogD (pH 5.5) 8.101 Log10 unitless📊 OPERA
LogD (pH 7.4) 8.101 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 9.64 Log10 unitless📊 OPERA
Water Solubility 0 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0 mmHg📊 OPERA
Viscosity 9.769 cP📊 OPERA
Surface Tension 31.657 dyn/cm📊 OPERA
Thermal Conductivity 140.954 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 9.23 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 12 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 93.042 cm^3/mol📊 OPERA
Polarizability 36.885 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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