2-Methyl-4-phenyl-2-butanol (CAS 0103-05-09) — Floral Heart Note Fragrance Ingredient

Floral · Woody

2-Methyl-4-phenyl-2-butanol

CAS 0103-05-09

Origin
synthetic
Note
Heart
IFRA
Use with awareness
Data as of: Apr 2026

What Is 2-Methyl-4-phenyl-2-butanol?

2-Methyl-4-phenyl-2-butanol is a synthetic fragrance ingredient used in perfumes and scented products. It contributes a unique aromatic character that enhances floral and woody compositions. This molecule matters because it helps create long-lasting, complex scent profiles while being more stable than some natural alternatives.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
IFRA compliant at standard usage levels
Limited toxicology data available
CAS
0103-05-09
Formula
Mixture
MW
Variable
Odor Family
Floral · Woody
Layer 1 · Enthusiast

What Does 2-Methyl-4-phenyl-2-butanol Smell Like?

A sophisticated aroma blending fresh floralcy with subtle woody undertones. Opens with crisp green nuances reminiscent of crushed stems, evolving into a rosy heart with hints of peony. The dry-down reveals a smooth, ambery base with exceptional tenacity. Acts as a harmonizer between bright top notes and deeper base materials.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Eternity Air(Calvin Klein, 2019)

Used as a modern floral enhancer, providing lift to the aquatic accord while adding subtle rosy-woody depth that prevents the composition from becoming too sharp.

Chance Eau Tendre(Chanel, 2010)

Employed as a bridge between the grapefruit top and jasmine heart, contributing a polished fruity-floral character that enhances diffusion.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

A tertiary alcohol with phenyl substitution, synthesized through Grignard reactions or hydroformylation routes. The branched carbon chain and hydroxyl group create unique steric effects that influence volatility and odor characteristics. Lacks chiral centers but exhibits conformational flexibility that contributes to its multifaceted scent profile.

Physical & Chemical Properties

Boiling Point245 °C (estimated)
Density0.98 g/cm³ (estimated)

Perfumer Guide

Note Position
Heart
Volatility
Medium (2-4 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-3%Up to 5%Floral compositions
Functional Products0.1-0.5%Up to 1%Fabric conditioners

Classic Accords

Tip: Use with citrus materials to prevent excessive sweetness in floral compositions.

Alternatives & Comparisons

1
Phenethyl alcohol CAS 60-12-8

For simpler rosy profiles when less woody complexity is desired.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No current IFRA restrictions. Listed on IFRA Transparency List.

RIFM Assessment

Under evaluation by RIFM as of 2023.

Sustainability

Synthesized from petrochemical precursors with moderate atom economy. No known ecological toxicity concerns at current production volumes. Offers advantages over natural extracts in consistency and yield.

Explore 2-Methyl-4-phenyl-2-butanol

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References

  1. Brenna et al. (2012). Synthetic routes to phenylbutanols. Journal of Organic Chemistry. DOI:10.1021/jo300456h

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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