Diethylene glycol monoethyl ether (CAS 111-90-0) — Sweet Carrier Note Fragrance Ingredient

Sweet · Citrus

Diethylene glycol monoethyl ether

CAS 111-90-0

Origin
synthetic
Note
Carrier
IFRA
Use with awareness
Data as of: Apr 2026

What Is Diethylene glycol monoethyl ether?

Diethylene glycol monoethyl ether is a synthetic solvent commonly found in industrial cleaners, paints, and some cosmetic formulations. It helps dissolve other ingredients and adjust product viscosity. While not a primary fragrance ingredient, it occasionally appears as a carrier solvent in perfumery where its mild properties aid in blending.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
Industrial solvent with limited cosmetic use
Potential skin irritant in high concentrations
CAS
111-90-0
Formula
Mixture
MW
Variable
Odor Family
Sweet · Citrus
Layer 1 · Enthusiast

What Does Diethylene glycol monoethyl ether Smell Like?

Diethylene glycol monoethyl ether has a faint, slightly sweet ether-like odor that dissipates quickly. Its scent profile is neutral and unobtrusive, making it more functional than aromatic. In formulations, it contributes minimal olfactory impact while serving as an effective solvent carrier for more volatile fragrance compounds.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Layer 2

2D Molecular Structure

2-(2-Ethoxyethoxy)ethanol

SMILES: CCOCCOCCO

Chemistry, Properties & Perfumer Guide

The Chemistry

Diethylene glycol monoethyl ether is an ethylene glycol ether formed by the reaction of ethylene oxide with ethanol. As a synthetic compound, it’s produced through controlled etherification processes in industrial settings. Its molecular structure features two ethylene glycol units terminated with an ethyl group, giving it balanced hydrophilic-lipophilic properties.

Physical & Chemical Properties

Boiling Point202 °C
Density0.99 g/cm³
Flash Point96 °C

Perfumer Guide

Note Position
Carrier
Volatility
Medium
Blending
Functional
ApplicationTypical %RangeNotes
Industrial Formulations5-20%Up to 50%Primary solvent
Cosmetic Carrier1-5%Up to 10%Limited fragrance use

Classic Accords

Tip: Use as a neutral carrier solvent when ethanol sensitivity is a concern.

Alternatives & Comparisons

1
Dipropylene glycol CAS 25265-71-8

Milder alternative with similar solvent properties and lower irritation potential.

2
Ethoxydiglycol CAS 111-90-0

Higher purity grade with cosmetic applications where solvent properties are needed.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not restricted by IFRA

GHS Classification

H319 Eye irritation

RIFM Assessment

Not evaluated by RIFM for fragrance use.

Sustainability

As a petrochemical-derived synthetic, its environmental impact stems from fossil fuel dependence in production. While biodegradable under aerobic conditions, its manufacturing carries typical hydrocarbon processing concerns. Limited fragrance use minimizes ecological footprint compared to industrial applications.

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References

  1. PubChem Compound Summary for Diethylene glycol monoethyl ether PubChem CID

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 111-90-0

Physical Properties

Molecular Weight134.17 g/mol🔬 PubChem
LogP (Octanol-Water)-0.5🔬 PubChem
Boiling Point202.2 °C🔬 EPA CompTox
Vapor Pressure0.13 mmHg @ 25°C📊 OPERA
Flash Point96.1 °C🔬 EPA CompTox
Involatility Index0.0121💻 Calculated
log Kp (skin permeability)-3.873💻 Calculated
SMILESCCOCCOCCO🔬 PubChem

Volatility & Performance

Fragrance NoteHeart💻 Calculated
Volatility ClassSlow💻 Calculated
Persistence Score0.8 / 5💻 Calculated

Odor & Flavor

Primary Descriptorscitrussweet• leffingwell
Functional Groupsalcoholether💻 RDKit
“Faint, ethereal odor with a musty undertone. Bitter taste is perceptible at concentrations above 20 ppm.”📖 Arctander

Flavor Notes (Arctander)

“Faint, ethereal odor with a musty undertone. Bitter taste is perceptible at concentrations above 20 ppm. This chemical is used mainly as a solvent for perfume materials, not suitable for flavors. It is considered more toxic than Ethylene glycol, and therefore banned from food flavors in most countri”📖 Arctander

Sensory Thresholds

Odor Detection Threshold0.489 ppm (n=2)📖 van Gemert
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID2021941

Physical Properties

Molecular Weight 134.175 g/mol🔬 EPA CompTox
Density 0.99 g/cm^3🔬 EPA CTX
Boiling Point 199.089 °C🔬 EPA CTX
Melting Point -75.536 °C🔬 EPA CTX
Flash Point 93.469 °C🔬 EPA CTX
Refractive Index 1.42 Dimensionless📊 OPERA
Molar Volume 137.807 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) -0.432 Log10 unitless🔬 EPA CTX
LogD (pH 5.5) -0.412 Log10 unitless📊 OPERA
LogD (pH 7.4) -0.417 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 5.64 Log10 unitless📊 OPERA
Water Solubility 7.451 mol/L🔬 EPA CTX
Henry's Law Constant 0 atm-m3/mole🔬 EPA CTX

Transport Properties

Vapor Pressure 0.123 mmHg🔬 EPA CTX
Viscosity 5.689 cP📊 OPERA
Surface Tension 32.813 dyn/cm📊 OPERA
Thermal Conductivity 173.157 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 38.69 Ų💻 Computed
H-Bond Donors 1 count💻 Computed
H-Bond Acceptors 3 count💻 Computed
Rotatable Bonds 6 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 34.871 cm^3/mol📊 OPERA
Polarizability 13.824 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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