Acetaldehyde ethyl phenylethyl acetal (CAS 2556-10-7) — Floral Top Note Fragrance Ingredient

Floral · Green

Acetaldehyde ethyl phenylethyl acetal

CAS 2556-10-7

Origin
synthetic
Note
Top
IFRA
Generally safe
Data as of: Apr 2026

What Is Acetaldehyde ethyl phenylethyl acetal?

Acetaldehyde ethyl phenylethyl acetal is a synthetic fragrance ingredient used to add green, floral, and slightly fruity nuances to perfumes. It’s commonly found in fine fragrances and personal care products. This ingredient matters because it enhances freshness and complexity in scent compositions, often contributing to the top notes that create first impressions.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for individual sensitivity
CAS
2556-10-7
Formula
Mixture
MW
Variable
Odor Family
Floral · Green
Layer 1 · Enthusiast

What Does Acetaldehyde ethyl phenylethyl acetal Smell Like?

Acetaldehyde ethyl phenylethyl acetal offers a crisp, green opening with floral undertones, reminiscent of freshly cut stems and dewy petals. As it evolves, it reveals a subtle fruity sweetness, like ripe pears in a sunlit orchard. The dry-down is clean and slightly woody, leaving a transparent trail that blends seamlessly with other notes.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Chanel No. 5(Chanel, 1921)

Used to enhance the floral bouquet, adding a fresh green lift to the iconic aldehydic opening.

Dior J'adore(Dior, 1999)

Contributes to the sparkling top notes, complementing the floral heart with its crisp green character.

Layer 2

2D Molecular Structure

[2-(1-Ethoxyethoxy)ethyl]benzene

SMILES: CCOC(C)OCCC1=CC=CC=C1

Chemistry, Properties & Perfumer Guide

The Chemistry

Acetaldehyde ethyl phenylethyl acetal is a synthetic acetal derived from acetaldehyde and phenylethyl alcohol. It belongs to the class of acetals, which are known for their stability and fresh olfactory profiles. The compound is typically synthesized through acid-catalyzed reactions, offering good yield and purity for perfumery applications.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Top
Volatility
Medium (1-2 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-3%Up to 5%Adds fresh green floral nuances
Personal Care0.5-2%Up to 3%Enhances freshness in soaps and lotions

Classic Accords

Tip: Use in small amounts to brighten floral compositions without overpowering.

Alternatives & Comparisons

1
Phenylethyl Acetate CAS 103-45-7

Offers a similar floral character but with more pronounced rosy notes.

2
Hexyl Acetate CAS 142-92-7

Provides a fruity green note, though less floral than the acetal.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No IFRA restrictions currently apply to this ingredient.

RIFM Assessment

RIFM has assessed this ingredient as safe for use in current practices.

Sustainability

As a synthetic ingredient, acetaldehyde ethyl phenylethyl acetal is produced in controlled environments with minimal environmental impact. Its synthesis avoids the need for natural resource extraction, making it a sustainable choice for modern perfumery.

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References

  1. PubChem Compound Summary for Acetaldehyde ethyl phenylethyl acetal PubChem

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID6051930

Physical Properties

Molecular Weight 194.274 g/mol🔬 EPA CompTox
Density 0.959 g/cm^3🔬 EPA CTX
Boiling Point 248.2 °C🔬 EPA CTX
Melting Point 0.122 °C📊 OPERA
Flash Point 104 °C🔬 EPA CTX
Refractive Index 1.486 Dimensionless📊 OPERA
Molar Volume 201.379 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 3.5 Log10 unitless🔬 EPA CTX
LogD (pH 5.5) 2.729 Log10 unitless📊 OPERA
LogD (pH 7.4) 2.729 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 6.1 Log10 unitless📊 OPERA
Water Solubility 0.002 mol/L🔬 EPA CTX
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.023 mmHg🔬 EPA CTX
Viscosity 3.559 cP📊 OPERA
Surface Tension 32.942 dyn/cm📊 OPERA
Thermal Conductivity 135.211 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 18.46 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 2 count💻 Computed
Rotatable Bonds 6 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 57.783 cm^3/mol📊 OPERA
Polarizability 22.907 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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