Carbonic acid, 2-hydroxypropyl (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester (CAS 260781-16-6) — Woody Base Note Fragrance Ingredient

Woody · Balsamic

Carbonic acid, 2-_hydroxypropyl (1R,_2S,_5R)_-_5-_methyl-_2-_(1-_methylethyl)_cyclohexyl ester

CAS 260781-16-6

Origin
synthetic
Note
Base
IFRA
Generally safe
Data as of: Apr 2026

What Is Carbonic acid, 2-_hydroxypropyl (1R,_2S,_5R)_-_5-_methyl-_2-_(1-_methylethyl)_cyclohexyl ester?

Carbonic acid, 2-hydroxypropyl (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester is a synthetic fragrance ingredient used in niche perfumery for its unique aromatic properties. It is encountered in high-end fragrances where complex, long-lasting scent profiles are desired. This ingredient matters because it offers perfumers a versatile tool for creating sophisticated accords with excellent stability and diffusion.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for individual sensitivity
CAS
260781-16-6
Formula
Mixture
MW
Variable
Odor Family
Woody · Balsamic
Layer 1 · Enthusiast

What Does Carbonic acid, 2-_hydroxypropyl (1R,_2S,_5R)_-_5-_methyl-_2-_(1-_methylethyl)_cyclohexyl ester Smell Like?

This synthetic ester delivers a nuanced olfactory profile, opening with a crisp, slightly citrusy top note that evolves into a heart of warm, woody nuances with a hint of spice. The dry-down reveals a smooth, balsamic character that lingers subtly on the skin, providing excellent tenacity and depth.

Scent Profile
Layer 2

2D Molecular Structure

Carbonic acid, 2-hydroxypropyl (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester

SMILES: CC(O)COC(=O)O[C@@H]1C[C@H](C)CC[C@H]1C(C)C

Chemistry, Properties & Perfumer Guide

The Chemistry

This compound is a synthetic ester derived from carbonic acid and a menthol derivative. It belongs to the class of cyclic carbonates, known for their stability and unique scent profiles. The synthesis typically involves the reaction of a diol with phosgene or a carbonate equivalent, followed by purification to achieve the desired stereochemistry.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Base
Volatility
Low (hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-5%Up to 10%Adds depth and longevity
Functional Fragrance0.5-2%Up to 5%Used for stability

Classic Accords

Tip: Use in base notes to enhance woody and balsamic accords.

Alternatives & Comparisons

1
Menthyl carbonate CAS 16541-52-3

A simpler analog with similar woody-balsamic properties but less complexity.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No IFRA restrictions currently apply.

RIFM Assessment

No RIFM safety assessment currently available.

Sustainability

As a synthetic ingredient, its production is controlled and does not rely on natural resources. Environmental impact depends on the synthesis route and waste management practices.

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References

    Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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    Physicochemical Properties

    DTXSID: DTXSID5074399

    Physical Properties

    Molecular Weight 258.358 g/mol🔬 EPA CompTox
    Density 1.014 g/cm^3🔬 EPA CTX
    Boiling Point 320.514 °C📊 OPERA
    Melting Point 30.162 °C📊 OPERA
    Flash Point 153 °C🔬 EPA CTX
    Refractive Index 1.469 Dimensionless📊 OPERA
    Molar Volume 250.922 cm^3/mol📊 OPERA

    Partition & Solubility

    LogP (Octanol-Water) 3.72 Log10 unitless🔬 EPA CTX
    LogD (pH 5.5) 3.669 Log10 unitless📊 OPERA
    LogD (pH 7.4) 3.784 Log10 unitless📊 OPERA
    LogKoa (Octanol-Air) 9.25 Log10 unitless📊 OPERA
    Water Solubility 0 mol/L🔬 EPA CTX
    Henry's Law Constant 0 atm-m3/mole📊 OPERA

    Transport Properties

    Vapor Pressure 0 mmHg🔬 EPA CTX
    Viscosity 22.278 cP📊 OPERA
    Surface Tension 33.736 dyn/cm📊 OPERA

    Molecular Descriptors

    Topological Polar Surface Area 55.76 Ų💻 Computed
    H-Bond Donors 1 count💻 Computed
    H-Bond Acceptors 4 count💻 Computed
    Rotatable Bonds 4 count💻 Computed
    Aromatic Rings 0 count💻 Computed
    Molar Refractivity 69.844 cm^3/mol📊 OPERA
    Polarizability 27.688 Å^3📊 OPERA

    Data Sources:

    🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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