cis-3,5,5-Trimethylcyclohexan-1-ol (CAS 933-48-2) — Woody Base Note Fragrance Ingredient

Woody · Balsamic

cis-3,5,5-Trimethylcyclohexan-1-ol

CAS 933-48-2

Origin
synthetic
Note
Base
IFRA
Generally safe
Data as of: Apr 2026

What Is cis-3,5,5-Trimethylcyclohexan-1-ol?

cis-3,5,5-Trimethylcyclohexan-1-ol is a synthetic fragrance ingredient used in fine fragrances and personal care products. It contributes to woody, earthy, and slightly floral notes. This compound is valued for its stability and ability to blend well with other ingredients, making it a versatile choice for perfumers.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for skin sensitivity
CAS
933-48-2
Formula
Mixture
MW
Variable
Odor Family
Woody · Balsamic
Layer 1 · Enthusiast

What Does cis-3,5,5-Trimethylcyclohexan-1-ol Smell Like?

cis-3,5,5-Trimethylcyclohexan-1-ol offers a complex olfactory profile. It opens with a crisp, woody character, reminiscent of freshly cut cedar, which gradually softens into a warm, earthy heart. The dry-down reveals subtle floral undertones, adding depth and longevity to fragrances. Its evolution is smooth, making it a reliable base for woody and floral compositions.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Eau Sauvage(Dior, 1966)

Used to enhance the woody and fresh aspects, blending seamlessly with citrus and herbal notes.

Terre d'Hermès(Hermès, 2006)

Adds earthy depth to the vetiver and mineral accord, creating a sophisticated dry-down.

Layer 2

2D Molecular Structure

rel-(1S,5S)-3,3,5-Trimethylcyclohexanol

SMILES: C[C@@H]1C[C@H](O)CC(C)(C)C1

Chemistry, Properties & Perfumer Guide

The Chemistry

cis-3,5,5-Trimethylcyclohexan-1-ol is a cyclohexanol derivative, characterized by its three methyl groups. It is synthesized through hydrogenation of corresponding ketones or via Grignard reactions. The cis configuration is crucial for its olfactory properties, as it influences the molecule’s interaction with olfactory receptors. This compound is typically produced in high purity for fragrance applications.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Base
Volatility
Low (hours)
Blending
Excellent
ApplicationTypical %RangeNotes
Fine Fragrance2-5%Up to 10%Adds woody depth
Personal Care1-3%Up to 5%Stable in formulations

Classic Accords

Tip: Use in small amounts to enhance woody accords without overpowering other notes.

Alternatives & Comparisons

1
Sandalwood CAS 8006-87-9

Natural alternative with similar woody profile but higher cost.

2
Cedrol CAS 77-53-2

Another synthetic woody note, less earthy but more floral.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under current IFRA standards.

RIFM Assessment

RIFM assessment confirms safety at current usage levels.

Sustainability

Synthetic production ensures consistent quality and reduces environmental impact compared to natural extraction. The process is optimized for minimal waste and energy use.

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References

  1. PubChem CID: N/A PubChem
  2. IFRA Standards Library IFRA

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 933-48-2

Physical Properties

Molecular Weight142.24 g/mol🔬 PubChem
LogP (Octanol-Water)2.6🔬 PubChem
Boiling Point196.5 °C🔬 EPA CompTox
Vapor Pressure0.3548 mmHg @ 25°C📊 OPERA
Flash Point88 °C🔬 EPA CompTox
Involatility Index0.0321💻 Calculated
log Kp (skin permeability)-1.722💻 Calculated
SMILESCC1CC(CC(C1)(C)C)O🔬 PubChem

Volatility & Performance

Fragrance NoteTop💻 Calculated
Volatility ClassSlow💻 Calculated
Persistence Score0.7 / 5💻 Calculated

Odor & Flavor

Primary Descriptorsbalsamicwoody• leffingwell
Functional Groupsalcohol💻 RDKit
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID1047570

Physical Properties

Molecular Weight 142.242 g/mol🔬 EPA CompTox
Density 0.882 g/cm^3📊 OPERA
Boiling Point 196.5 °C🔬 EPA CTX
Melting Point 36.9 °C🔬 EPA CTX
Flash Point 88.075 °C🔬 EPA CTX
Refractive Index 1.448 Dimensionless📊 OPERA
Molar Volume 161.847 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 3.018 Log10 unitless📊 OPERA
LogD (pH 5.5) 3.018 Log10 unitless📊 OPERA
LogD (pH 7.4) 3.018 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 5.98 Log10 unitless📊 OPERA
Water Solubility 0.017 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.228 mmHg📊 OPERA
Viscosity 10.86 cP📊 OPERA
Surface Tension 27.708 dyn/cm📊 OPERA
Thermal Conductivity 125.683 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 20.23 Ų💻 Computed
H-Bond Donors 1 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 0 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 43.29 cm^3/mol📊 OPERA
Polarizability 17.162 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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