Dihydropinene (CAS 473-55-2) — Woody Top to middle Note Fragrance Ingredient
Dihydropinene
CAS 473-55-2
What Is Dihydropinene?
Dihydropinene is a synthetic fragrance ingredient used in modern perfumery to add woody, pine-like freshness. It’s found in air fresheners, masculine colognes, and cleaning products. This versatile material helps create crisp, outdoorsy scents that evoke forest walks and alpine freshness.
Safety Profile
GENERALLY SAFEWhat Does Dihydropinene Smell Like?
Dihydropinene delivers a sharp, clean pine needle character with camphoraceous undertones. The initial burst is intensely fresh – like crushed pine cones and winter air. As it evolves, reveals a smoother woody heart with subtle citrusy facets. The dry-down leaves a subtle, clean woody trace that blends well with other forest notes.
In Famous Fragrances
Fragrance associations may not reflect actual formulations.
Used as a key pine note to create the authentic Italian forest accord, blending with juniper and citrus for a classic barbershop freshness.
Provides crisp contrast to vanilla base notes, creating an unusual forest-gourmand juxtaposition in this niche composition.
2D Molecular Structure
SMILES: CC1CCC2CC1C2(C)C
Chemistry, Properties & Perfumer Guide
The Chemistry
Dihydropinene is a bicyclic monoterpene derivative, structurally related to pinene but with reduced double bonds. It’s typically synthesized through hydrogenation of pinene precursors. The saturated structure makes it more stable than pinene while retaining similar olfactory characteristics. Commercial production often uses turpentine-derived feedstocks.
Physical & Chemical Properties
| Boiling Point | Not specified |
|---|---|
| Density | Not specified |
Perfumer Guide
| Application | Typical % | Range | Notes |
|---|---|---|---|
| Fine Fragrance | 1-3% | Up to 5% | Forest accords, masculine fougères |
| Functional Fragrances | 3-8% | Up to 15% | Cleaning products, air fresheners |
Classic Accords
Tip: Use to add crispness to woody bases without overwhelming citrus top notes.
Alternatives & Comparisons
More volatile with sharper pine character, but less stable in formulations.
Offers similar woody freshness but with floral citrus nuances.
Safety, Regulatory & Sustainability
⚠ Regulatory Disclaimer
General reference only. Consult current IFRA Standards Library before formulating.
IFRA Status
No IFRA restrictions currently apply to dihydropinene.
RIFM Assessment
Not currently assessed by RIFM, but structurally similar compounds have good safety profiles.
Sustainability
As a synthetic material, dihydropinene production doesn’t impact natural pine forests. Most commercial production uses byproducts from paper industry turpentine, making it a sustainable use of existing waste streams. Carbon footprint depends on hydrogenation process energy inputs.
Explore Dihydropinene
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References
- Bauer et al. (2001). Common Fragrance and Flavor Materials. Wiley-VCH.
- Turpentine Derivatives Technical Report
Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.
Report a data errorIngredient Data Sheet
CAS 473-55-2Physical Properties
| Molecular Weight | 138.25 g/mol🔬 PubChem |
| LogP (Octanol-Water) | 3.9🔬 PubChem |
| Boiling Point | 151.1 °C🔬 EPA CompTox |
| Vapor Pressure | 2 mmHg @ 25°C📊 OPERA |
| Flash Point | 40 °C🔬 EPA CompTox |
| Involatility Index | 0.1833💻 Calculated |
| log Kp (skin permeability) | -0.774💻 Calculated |
| SMILES | CC1CCC2CC1C2(C)C🔬 PubChem |
Volatility & Performance
| Fragrance Note | Top💻 Calculated |
| Volatility Class | Moderate💻 Calculated |
| Persistence Score | 0.5 / 5💻 Calculated |
Odor & Flavor
| Primary Descriptors | greenpinewoody• leffingwell |
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.
Physicochemical Properties
DTXSID: DTXSID7025922
Physical Properties
| Molecular Weight | 138.254 g/mol🔬 EPA CompTox |
| Density | 0.847 g/cm^3🔬 EPA CTX |
| Boiling Point | 160.037 °C🔬 EPA CTX |
| Melting Point | -51.5 °C🔬 EPA CTX |
| Flash Point | 40.075 °C🔬 EPA CTX |
| Refractive Index | 1.455 Dimensionless📊 OPERA |
| Molar Volume | 163.619 cm^3/mol📊 OPERA |
Partition & Solubility
| LogP (Octanol-Water) | 4.403 Log10 unitless📊 OPERA |
| LogD (pH 5.5) | 4.403 Log10 unitless📊 OPERA |
| LogD (pH 7.4) | 4.403 Log10 unitless📊 OPERA |
| LogKoa (Octanol-Air) | 4.56 Log10 unitless📊 OPERA |
| Water Solubility | 0 mol/L📊 OPERA |
| Henry's Law Constant | 0.059 atm-m3/mole📊 OPERA |
Transport Properties
| Vapor Pressure | 3.329 mmHg🔬 EPA CTX |
| Viscosity | 2.052 cP📊 OPERA |
| Surface Tension | 27.075 dyn/cm📊 OPERA |
| Thermal Conductivity | 104.417 mW/(m*K)📊 OPERA |
Molecular Descriptors
| Topological Polar Surface Area | 0 Ų💻 Computed |
| H-Bond Donors | 0 count💻 Computed |
| H-Bond Acceptors | 0 count💻 Computed |
| Rotatable Bonds | 0 count💻 Computed |
| Aromatic Rings | 0 count💻 Computed |
| Molar Refractivity | 44.364 cm^3/mol📊 OPERA |
| Polarizability | 17.587 Å^3📊 OPERA |
Data Sources:
🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.
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