Ethyl safranate (CAS 35044-57-6) — Floral Top to Middle Note Fragrance Ingredient

Floral · Sweet

Ethyl safranate

CAS 35044-57-6

Origin
synthetic
Note
Top to Middle
IFRA
Generally safe
Data as of: Apr 2026

What Is Ethyl safranate?

Ethyl safranate is a synthetic aroma compound used to add fruity, floral, and slightly woody nuances to fragrances. You’ll encounter it in high-end perfumes and some luxury body care products. This ingredient matters because it can mimic rare natural aromas at a fraction of the cost, making sophisticated scents more accessible while avoiding supply chain issues of natural alternatives.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
No major safety concerns at typical usage levels
Always follow IFRA guidelines for maximum concentrations
CAS
35044-57-6
Formula
Mixture
MW
Variable
Odor Family
Floral · Sweet
Layer 1 · Enthusiast

What Does Ethyl safranate Smell Like?

Ethyl safranate opens with a bright burst reminiscent of overripe apricots and plum jam, with a subtle metallic edge like saffron threads on copper. The heart reveals a surprising floralcy – imagine gardenias dipped in honey, while the dry-down lingers as a soft woody-musk akin to sandalwood sawdust. Its tenacity is moderate (4-6 hours), transitioning smoothly from fruity top to creamy base without sharp edges.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Saffron Troublant(L’Artisan Parfumeur, 2007)

Used here to create the illusion of precious saffron without the spice’s harshness, blending seamlessly with vanilla and sandalwood.

Baccarat Rouge 540(Maison Francis Kurkdjian, 2015)

Provides the candied fruit facet that makes this ambery fragrance so addictive, complementing the ambergris accord.

Layer 2

2D Molecular Structure

Ethyl 2,6,6-trimethylcyclohexa-2,4-diene-1-carboxylate

SMILES: CCOC(=O)C1C(C)=CC=CC1(C)C

Chemistry, Properties & Perfumer Guide

The Chemistry

Ethyl safranate is an ester derivative with a molecular weight of 194.23 g/mol. While not found in nature, it’s structurally similar to compounds in saffron and certain fruits. Industrially produced via esterification reactions under controlled conditions, its synthesis allows precise control over stereochemistry – crucial since even minor structural changes dramatically alter odor profiles. The ethyl ester group enhances volatility compared to bulkier counterparts.

Physical & Chemical Properties

Molecular Weight194.23 g/mol
Boiling Point~250 °C (estimated)

Perfumer Guide

Note Position
Top to Middle
Volatility
Medium (2-4 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-3%0.5-5%Adds fruity-floral complexity
Body Care0.2-1%0.1-2%Use sparingly for luxury effect

Classic Accords

+ Vanilla + Sandalwood = Golden Gourmand + Rose Oxide + Cashmeran = Modern Chypre

Tip: Use in traces with white florals to prevent candied overtones from dominating.

Alternatives & Comparisons

1
Safraleine CAS 32388-55-9

When more leathery-saffron character is desired, though requires dosage adjustments due to greater potency.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No current IFRA restrictions (as of Amendment 51).

RIFM Assessment

RIFM has reviewed ethyl safranate and found it safe for current fragrance use patterns.

Sustainability

As a synthetic material, ethyl safranate avoids agricultural impacts of natural saffron production. Its efficient synthesis from petrochemical precursors has relatively low carbon footprint compared to crop-derived aroma chemicals. Future bio-synthesis routes may further improve sustainability.

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References

  1. PubChem Compound Summary for Ethyl safranate PubChem
  2. IFRA Standards Library IFRA

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 35044-57-6

Physical Properties

Molecular Weight194.27 g/mol🔬 PubChem
LogP (Octanol-Water)2.9🔬 PubChem
Boiling Point235 °C🔬 EPA CompTox
Vapor Pressure0.0204 mmHg @ 25°C📊 OPERA
Flash Point90.2 °C🔬 EPA CompTox
Involatility Index0.0016💻 Calculated
log Kp (skin permeability)-1.826💻 Calculated
SMILESCCOC(=O)C1C(=CC=CC1(C)C)C🔬 PubChem

Volatility & Performance

Fragrance NoteHeart💻 Calculated
Volatility ClassVery slow💻 Calculated
Persistence Score3.1 / 5💻 Calculated

Odor & Flavor

Primary Descriptorsapplefruityherbalspicy• leffingwell
Functional Groupsesteretheralkene💻 RDKit
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID7052026

Physical Properties

Molecular Weight 194.274 g/mol🔬 EPA CompTox
Density 0.957 g/cm^3📊 OPERA
Boiling Point 236.24 °C📊 OPERA
Melting Point 20.478 °C📊 OPERA
Flash Point 94.278 °C📊 OPERA
Refractive Index 1.467 Dimensionless📊 OPERA
Molar Volume 203.558 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 3.823 Log10 unitless📊 OPERA
LogD (pH 5.5) 3.823 Log10 unitless📊 OPERA
LogD (pH 7.4) 3.823 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 5.76 Log10 unitless📊 OPERA
Water Solubility 0.005 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.023 mmHg📊 OPERA
Viscosity 3.664 cP📊 OPERA
Surface Tension 28.301 dyn/cm📊 OPERA
Thermal Conductivity 129.836 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 26.3 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 2 count💻 Computed
Rotatable Bonds 2 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 56.487 cm^3/mol📊 OPERA
Polarizability 22.393 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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