Methylionone (CAS 1335-94-0) — Floral Heart Note Fragrance Ingredient

Floral · Sweet

Methylionone

CAS 1335-94-0

Origin
synthetic
Note
Heart
IFRA
Generally safe
Data as of: Apr 2026

What Is Methylionone?

Methylionone is a synthetic fragrance ingredient that creates a soft, powdery violet-like scent. You’ll find it in perfumes, soaps, and fabric softeners where it adds a floral-woody character. This versatile molecule helps perfumers recreate the scent of violets without using natural extracts, making fragrances more affordable and consistent year-round.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
No major restrictions
Check for individual sensitivities
CAS
1335-94-0
Formula
Mixture
MW
Variable
Odor Family
Floral · Sweet
Layer 1 · Enthusiast

What Does Methylionone Smell Like?

Methylionone unfolds like a vintage violet handkerchief – powdery floral at first, with a subtle raspberry-like fruitiness hiding beneath. The initial burst softens into a creamy, woody base that lingers close to the skin. Unlike sharper ionones, methylionone has a rounded character that blends seamlessly with sandalwood and musk, creating a velvety dry-down reminiscent of antique face powder.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Apres l'Ondee(Guerlain, 1906)

Methylionone creates the melancholic violet-iris heart of this classic, blending with heliotropin for a rain-soaked floral effect that feels both nostalgic and transparent.

Insolence(Guerlain, 2006)

Used in overdose here to create a modern violet explosion, methylionone’s powdery facets are amplified by ethyl maltol for a candied, contemporary interpretation.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Methylionone belongs to the ionone family of cyclic terpenoids, specifically a methyl-substituted derivative of α-ionone. While ionones occur naturally in violets and orris root, methylionone is exclusively synthetic. It’s typically produced through acid-catalyzed cyclization of pseudoionone derivatives. The methyl group at position 3 creates a more stable molecule with enhanced diffusion compared to unsubstituted ionones.

Physical & Chemical Properties

AppearanceColorless to pale yellow liquid
Boiling PointApprox. 250°C
Density~0.93 g/cm³

Perfumer Guide

Note Position
Heart
Volatility
Medium (2-6 hours)
Blending
Excellent
ApplicationTypical %RangeNotes
Fine Fragrance2-5%Up to 10%Heart note floralizer
Soap0.5-1.5%Up to 3%Stable in alkaline conditions

Classic Accords

+ Orris + Heliotropin = Powdery floral + Sandalwood + Vanillin = Oriental base

Tip: Combine with ionone gamma for enhanced diffusion and a more natural violet effect.

Alternatives & Comparisons

1
α-Ionone CAS 127-41-3

More natural violet character but less stable. Use when authenticity outweighs cost considerations.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under IFRA standards.

RIFM Assessment

Evaluated as safe for current use levels in fragrances (RIFM, 2015).

Sustainability

As a synthetic, methylionone avoids the sustainability issues of natural violet absolute production (which requires massive flower quantities). Modern synthesis routes have reduced solvent waste compared to traditional methods.

Explore Methylionone

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References

  1. Bauer et al. (2001). Common Fragrance and Flavor Materials. Wiley-VCH.

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 1335-94-0

Regulatory Status

IFRA ListedYes — see IFRA Standards for category limits⚖️ IFRA 51
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

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