Formic acid, reaction products with boron trifluoride and [1S-(1,3a,4,8a)]-decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene (CAS 68855-38-9) — Woody Base Note Fragrance Ingredient

Woody · Balsamic

Formic acid, reaction products with boron trifluoride and [1S-(1_,3a_,4_,8a_)]-decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene

CAS 68855-38-9

Origin
synthetic
Note
Base
IFRA
Professional use
Data as of: Apr 2026

What Is Formic acid, reaction products with boron trifluoride and [1S-(1_,3a_,4_,8a_)]-decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene?

This synthetic fragrance ingredient is a specialized chemical compound used in high-end perfumery. It’s typically encountered in niche fragrances where complex woody-amber accords are desired. The ingredient matters for creating sophisticated, long-lasting base notes that evolve beautifully on skin over time.

Safety Profile

PROFESSIONAL USE
Generally safeUse with awarenessProfessional use
Requires professional handling
Potential skin sensitizer
CAS
68855-38-9
Formula
Mixture
MW
Variable
Odor Family
Woody · Balsamic
Layer 1 · Enthusiast

What Does Formic acid, reaction products with boron trifluoride and [1S-(1_,3a_,4_,8a_)]-decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene Smell Like?

This complex synthetic molecule delivers a powerful woody-ambergris character with deep resinous undertones. The scent evolves from an initial sharp, almost metallic top note to a warm, animalic heart reminiscent of aged amber. The dry-down reveals a sophisticated woody-musky character that persists for hours, adding depth and tenacity to fragrance compositions.

Scent Profile
Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

This compound is a boron trifluoride-catalyzed reaction product of formic acid with a specific decahydromethanoazulene derivative. The synthesis creates a complex mixture of isomers with varying olfactory properties. The boron trifluoride catalyst enables the formation of unique molecular structures not found in nature.

Physical & Chemical Properties

AppearanceViscous liquid
ColorAmber to dark brown

Perfumer Guide

Note Position
Base
Volatility
Very low (8+ hours)
Blending
Moderate
ApplicationTypical %RangeNotes
Fine Fragrance0.1-0.5%Up to 1%Powerful base note modifier
Functional Fragrance0.01-0.1%Up to 0.2%Used sparingly for depth

Classic Accords

Tip: Use in trace amounts to avoid overwhelming compositions.

Alternatives & Comparisons

1
Ambroxan CAS 6790-58-5

A more widely available synthetic amber alternative with better safety profile.

2
Norlimbanol CAS 70788-30-6

Provides similar woody-amber character with greater stability.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No specific IFRA restrictions. Follow general guidelines for boron-containing compounds.

GHS Classification

H315 Skin irritation H319 Eye irritation H335 May cause respiratory irritation

RIFM Assessment

Not currently evaluated by RIFM. Use with caution.

Sustainability

As a synthetic material, production is controlled but requires specialized chemical processes. The boron trifluoride catalyst requires careful handling and disposal.

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References

    Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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    Ingredient Data Sheet

    CAS 68855-38-9
    Data Sources & Attribution
    Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

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