Glyceryl monooleate (CAS 0111-03-05) — Citrus Non-volatile Note Fragrance Ingredient

Citrus · Floral

Glyceryl monooleate

CAS 0111-03-05

Origin
synthetic
Note
Non-volatile
IFRA
Generally safe
Data as of: Apr 2026

What Is Glyceryl monooleate?

Glyceryl monooleate is a synthetic ingredient primarily used as an emulsifier in cosmetics and skincare products. You’ll find it in lotions, creams, and some hair care formulations where it helps blend oil and water components. While not a traditional fragrance material, it plays a supporting role in product stability and texture.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Approved for cosmetic use worldwide
Non-toxic at typical usage levels
CAS
0111-03-05
Formula
Mixture
MW
Variable
Odor Family
Citrus · Floral
Layer 1 · Enthusiast

What Does Glyceryl monooleate Smell Like?

Glyceryl monooleate is essentially odorless with only a faint, neutral fatty character when pure. As a non-volatile emulsifier, it doesn’t contribute to fragrance profiles but serves as a carrier for scent molecules in cosmetic formulations. Its molecular structure helps stabilize volatile fragrance components without altering their olfactory characteristics.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Glyceryl monooleate is a monoglyceride derived from glycerol and oleic acid. It’s synthesized through esterification reactions, often using enzymatic or chemical catalysis. The molecule features a polar glycerol head group and a nonpolar oleic acid tail, giving it amphiphilic properties essential for its emulsifying function. Commercial grades typically contain mixtures of mono-, di-, and triglycerides.

Physical & Chemical Properties

AppearancePale yellow viscous liquid
SolubilitySoluble in oils, partially soluble in water

Perfumer Guide

Note Position
Non-volatile
Volatility
None
Blending
Functional
ApplicationTypical %RangeNotes
Cosmetic Emulsions1-5%0.5-10%Primary emulsifier
Fragrance Carrier2-8%1-15%Stabilizes volatile components

Classic Accords

Tip: Use as a base emulsifier to improve fragrance oil solubility in aqueous systems.

Alternatives & Comparisons

1
Polysorbate 20 CAS 9005-64-5

Water-soluble emulsifier for more polar fragrance systems

2
Glyceryl monostearate CAS 31566-31-1

Higher melting point alternative for solid formulations

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not restricted by IFRA – classified as non-fragrance ingredient

RIFM Assessment

Not evaluated by RIFM as it’s not a fragrance material.

Sustainability

Synthesized from renewable sources (glycerol and vegetable-derived oleic acid). Production typically uses green chemistry principles with high atom economy. Biodegradable under normal environmental conditions.

Explore Glyceryl monooleate

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References

  1. Cosmetic Ingredient Review (CIR) Expert Panel. (2017). Safety Assessment of Monoglycerides as Used in Cosmetics. CIR Report
  2. European Chemicals Agency (ECHA) Substance Information ECHA Entry

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Perfumer’s Notes

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