Isononyl propionate (CAS 65155-45-5) — Citrus Top to Middle Note Fragrance Ingredient

Citrus · Sweet

Isononyl propionate

CAS 65155-45-5

Origin
synthetic
Note
Top to Middle
IFRA
Generally safe
Data as of: Apr 2026

What Is Isononyl propionate?

Isononyl propionate is a synthetic ester used in fragrances to add fruity, floral, and slightly green nuances. It’s commonly found in perfumes, body lotions, and air fresheners. This ingredient matters because it enhances freshness and blends well with citrus and woody notes, making it versatile for modern scent compositions.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for individual sensitivity
CAS
65155-45-5
Formula
Mixture
MW
Variable
Odor Family
Citrus · Sweet
Layer 1 · Enthusiast

What Does Isononyl propionate Smell Like?

Isononyl propionate offers a crisp, fruity top note reminiscent of pear and apple skins, with a subtle floral undertone. As it evolves, it reveals a green, slightly herbaceous heart, settling into a clean, woody base. The dry-down is smooth and slightly sweet, making it a versatile bridge between fresh and warm accords.

Scent Profile
Layer 2

2D Molecular Structure

Isononyl propionate

SMILES: CCC(=O)OCCCCCCC(C)C

Chemistry, Properties & Perfumer Guide

The Chemistry

Isononyl propionate is an ester formed from isononyl alcohol and propionic acid. It is synthesized via esterification, a common reaction in fragrance chemistry. The molecule’s structure contributes to its fruity and floral odor profile, with moderate volatility making it suitable for top to middle notes in perfumery.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Top to Middle
Volatility
Moderate (1-2 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance2-5%Up to 10%Adds fruity freshness
Body Care1-3%Up to 5%Enhances floral notes

Classic Accords

Tip: Use to brighten floral compositions or add a fruity twist to woody accords.

Alternatives & Comparisons

1
Isoamyl acetate CAS 123-92-2

Offers a more pronounced banana-like fruity note, suitable for tropical or gourmand fragrances.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under IFRA standards.

RIFM Assessment

RIFM has assessed isononyl propionate as safe for use in fragrances at current levels.

Sustainability

Isononyl propionate is synthetically produced, reducing reliance on natural resources. Its production is efficient, with minimal environmental impact when handled responsibly.

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References

  1. PubChem: Isononyl propionate PubChem

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID1070270

Physical Properties

Molecular Weight 200.322 g/mol🔬 EPA CompTox
Density 0.866 g/cm^3📊 OPERA
Boiling Point 234.993 °C📊 OPERA
Melting Point -37.395 °C📊 OPERA
Flash Point 92.38 °C📊 OPERA
Refractive Index 1.429 Dimensionless📊 OPERA
Molar Volume 230.475 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 4.53 Log10 unitless📊 OPERA
LogD (pH 5.5) 4.53 Log10 unitless📊 OPERA
LogD (pH 7.4) 4.53 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 5.74 Log10 unitless📊 OPERA
Water Solubility 0 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.045 mmHg📊 OPERA
Viscosity 2.33 cP📊 OPERA
Surface Tension 27.449 dyn/cm📊 OPERA
Thermal Conductivity 136.075 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 26.3 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 2 count💻 Computed
Rotatable Bonds 8 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 59.377 cm^3/mol📊 OPERA
Polarizability 23.539 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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