Piper longum CO2 extract (CAS 90082-60-3) — Spicy Middle Note Fragrance Ingredient

Spicy · Balsamic

Piper longum CO2 extract

CAS 90082-60-3

Origin
natural
Note
Middle
IFRA
Use with awareness
Data as of: Apr 2026

What Is Piper longum CO2 extract?

Piper longum CO2 extract comes from the long pepper plant, a relative of black pepper. You’ll find it in spicy oriental fragrances and some artisanal food flavorings. This extract captures the plant’s complex aroma without harsh solvents. Its warm, peppery depth makes it valuable for perfumers creating rich, exotic accords.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
GRAS for food use
May cause skin sensitivity
CAS
90082-60-3
Formula
Mixture
MW
Variable
Odor Family
Spicy · Balsamic
Layer 1 · Enthusiast

What Does Piper longum CO2 extract Smell Like?

A deep, resinous pepperiness unfolds with earthy undertones reminiscent of aged woods and dried fruits. The initial burst is sharp and medicinal, quickly mellowing into a warm, almost chocolate-like richness. Unlike common black pepper, it carries a lingering sweet-balsamic character that blends beautifully with oriental bases. The dry-down reveals subtle camphoraceous facets that add complexity to spicy compositions.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Poivre Samarcande(Hermès, 2004)

Used for its exotic peppery warmth contrasting with citrus top notes. The CO2 extraction preserves delicate volatile compounds lost in steam distillation.

Blackpepper(Comme des Garçons, 2014)

Provides authentic pepper depth without harshness. The extract’s natural complexity creates a more rounded spice accord than synthetic alternatives.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Piper longum CO2 extract contains a complex mixture of piperine analogs, sesquiterpenes, and phenylpropanoids. Supercritical CO2 extraction at specific pressures selectively captures both volatile aromatics and heavier resinous compounds. This method avoids thermal degradation of heat-sensitive components present in traditional steam distillation. The extract’s composition varies by harvest time and plant part used (fruit vs. root).

Physical & Chemical Properties

AppearanceViscous amber liquid
SolubilitySoluble in ethanol and oils

Perfumer Guide

Note Position
Middle
Volatility
Moderate (2-4 hours)
Blending
Good with oriental bases
ApplicationTypical %RangeNotes
Fine Fragrance0.5-2%Up to 5%Spice modifier
Home Fragrance0.1-0.5%Up to 1%Warmth enhancer

Classic Accords

Tip: Combine with citrus top notes to prevent the pepper character from becoming too dominant.

Alternatives & Comparisons

1
Black Pepper EO CAS 8006-82-4

More pungent and linear. Use when brighter pepper notes are needed rather than deep complexity.

2
Cubebin CAS 500-20-1

Synthetic alternative for the woody-peppery aspects without the full natural profile.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No IFRA restrictions. Contains naturally occurring safrole below restricted levels.

GHS Classification

H315 Skin irritation

RIFM Assessment

RIFM monograph available. Considered safe at current use levels.

Sustainability

CO2 extraction uses renewable, non-toxic solvent that’s fully recycled. Sustainable wild harvesting practices are developing in India. The method yields more material per plant than distillation, reducing agricultural pressure.

Explore Piper longum CO2 extract

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References

  1. Parmar et al. (1997). Phytochemistry of Piper longum. Phytochemistry. DOI 10.1016/S0031-9422(96)00654-0

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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