Terpenes and terpenoids, mixed sour and sweet orange oil (CAS 68917-57-7) — Citrus Top Note Fragrance Ingredient

Citrus · Sweet

Terpenes and terpenoids, mixed sour and sweet orange oil

CAS 68917-57-7

Origin
natural
Note
Top
IFRA
Generally safe
Data as of: Apr 2026

What Is Terpenes and terpenoids, mixed sour and sweet orange oil?

Terpenes and terpenoids from mixed orange oils are natural compounds found in citrus peels. They’re used in food flavorings, household cleaners, and perfumes for their fresh, uplifting scent. These molecules contribute to the distinct aroma of oranges while offering antimicrobial properties, making them valuable in both fragrances and functional products.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Generally recognized as safe (GRAS) for food use
Potential skin sensitizer in high concentrations
CAS
68917-57-7
Formula
Mixture
MW
Variable
Odor Family
Citrus · Sweet
Layer 1 · Enthusiast

What Does Terpenes and terpenoids, mixed sour and sweet orange oil Smell Like?

The terpenes in orange oil burst with zesty, sun-warmed citrus peel character – think freshly grated orange zest with a candied edge. Initial brightness mellows into a juicy, slightly green sweetness reminiscent of marmalade. The terpenoids add depth with subtle woody-herbal undertones that emerge during dry-down, creating a more complex profile than pure limonene.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Eau Sauvage(Dior, 1966)

Uses orange terpenes to create its iconic fresh citrus opening, blending with rosemary and basil for a Mediterranean aromatic effect.

Orange Sanguine(Atelier Cologne, 2010)

Features blood orange terpenes prominently to achieve photorealistic citrus that lasts unusually long for a top note.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Orange oil terpenes primarily consist of limonene (up to 95%), with smaller amounts of myrcene, pinene, and sabinene. The terpenoid fraction includes oxygenated compounds like citral and linalool. These compounds are extracted via cold pressing of orange peels, with some subsequent fractional distillation to isolate specific components. The mix of mono- and sesquiterpenes creates both immediate freshness and subtle lasting power.

Physical & Chemical Properties

Boiling Point Range175-178°C (limonene)
Flash Point48°C
Refractive Index1.472-1.474

Perfumer Guide

Note Position
Top
Volatility
High (30-90 min)
Blending
Excellent
ApplicationTypical %RangeNotes
Fine Fragrance5-10%Up to 20%Citrus core component
Functional Fragrance0.5-2%Up to 5%Air fresheners, cleaners

Classic Accords

Tip: Combine with citrus aldehydes to extend freshness and prevent flatness in top notes.

Alternatives & Comparisons

1
Limonene CAS 138-86-3

Purified single terpene when more consistent citrus character is needed without orange oil’s complexity.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under IFRA 49th Amendment. Limonene content requires antioxidant stabilization.

EU Allergen Declaration

Limonene must be declared above 100 ppm due to oxidation products.

GHS Classification

H315 H317 H411

RIFM Assessment

RIFM safety assessment complete for food and fragrance use.

Sustainability

Orange terpenes are byproducts of juice production, making them highly sustainable. Cold pressing extraction maintains low carbon footprint compared to distillation. Some concerns exist about citrus greening disease affecting future supply stability.

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References

  1. Dharmawan et al. (2007). Characterization of volatile compounds in selected citrus fruits. Flavour and Fragrance Journal. Link

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 68917-57-7
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

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