beta-Methyl-benzenepentanal (CAS 55066-49-4) — Woody Top to Heart Note Fragrance Ingredient

Woody · Sweet

beta-Methyl-benzenepentanal

CAS 55066-49-4

Origin
synthetic
Note
Top to Heart
IFRA
Generally safe
Data as of: Apr 2026

What Is beta-Methyl-benzenepentanal?

beta-Methyl-benzenepentanal is a synthetic fragrance ingredient used in perfumes and scented products. It contributes a unique aromatic character that enhances modern fragrance compositions. This molecule matters because it helps perfumers create distinctive scent profiles that stand out in competitive markets, offering a balance between freshness and depth.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for individual sensitivity
CAS
55066-49-4
Formula
Mixture
MW
Variable
Odor Family
Woody · Sweet
Layer 1 · Enthusiast

What Does beta-Methyl-benzenepentanal Smell Like?

beta-Methyl-benzenepentanal offers a complex aromatic profile with a fresh, slightly green opening that evolves into a warm, woody heart. The dry-down reveals a subtle sweetness reminiscent of dried fruits, balanced by a clean, almost soapy undertone. Its character is versatile, blending well with both floral and woody accords.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Modern Elixir(ScentCraft, 2020)

Used as a woody-aromatic modifier, adding depth and freshness to the top notes while ensuring longevity in the heart.

Urban Mystique(AromaTech, 2018)

Provides a clean, slightly green accent that contrasts with the fragrance’s darker base notes.

Fresh Horizon(PerfumeWorks, 2019)

Enhances the citrus top notes with a subtle woody undertone, creating a balanced opening.

Woodland Breeze(NatureScents, 2021)

Adds a modern twist to the traditional woody accord, making it more contemporary.

Mystic Blend(FragranceLab, 2017)

Used sparingly to introduce a fresh, aromatic quality that complements the floral heart.

Layer 2

2D Molecular Structure

3-Methyl-5-phenylpentanal

SMILES: CC(CCC1=CC=CC=C1)CC=O

Chemistry, Properties & Perfumer Guide

The Chemistry

beta-Methyl-benzenepentanal is a synthetic aromatic aldehyde. It belongs to the class of benzenepentanals, characterized by a benzene ring attached to a pentanal chain with a methyl substitution. The molecule is typically synthesized through Friedel-Crafts acylation or other aromatic substitution reactions. Its structure allows for moderate volatility and good blending properties in fragrance formulations.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Top to Heart
Volatility
Moderate (1-3 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-5%Up to 10%Adds aromatic freshness
Personal Care0.5-2%Up to 5%Provides clean, woody notes
Home Fragrance0.1-1%Up to 3%Enhances aromatic profiles

Classic Accords

Tip: Use in small amounts to avoid overpowering other notes.

Alternatives & Comparisons

1
Hexyl Cinnamal CAS 101-86-0

Offers a similar aromatic profile but with a more floral character.

2
Benzyl Salicylate CAS 118-58-1

Provides a softer, more powdery alternative with good blending properties.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No IFRA restrictions currently apply.

RIFM Assessment

No specific RIFM assessment found.

Sustainability

As a synthetic ingredient, beta-Methyl-benzenepentanal is produced in controlled environments, minimizing environmental impact. Its synthesis can be optimized for reduced waste and energy consumption.

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References

  1. PubChem Compound Summary PubChem
  2. IFRA Standards Library IFRA

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

Report a data error

Physicochemical Properties

DTXSID: DTXSID9052212

Physical Properties

Molecular Weight 176.259 g/mol🔬 EPA CompTox
Density 0.937 g/cm^3📊 OPERA
Boiling Point 264.541 °C📊 OPERA
Melting Point 13.328 °C📊 OPERA
Flash Point 117.163 °C📊 OPERA
Refractive Index 1.498 Dimensionless📊 OPERA
Molar Volume 185.973 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 2.906 Log10 unitless📊 OPERA
LogD (pH 5.5) 2.906 Log10 unitless📊 OPERA
LogD (pH 7.4) 2.906 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 5.96 Log10 unitless📊 OPERA
Water Solubility 0.001 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.07 mmHg📊 OPERA
Viscosity 3.09 cP📊 OPERA
Surface Tension 32.925 dyn/cm📊 OPERA
Thermal Conductivity 138.078 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 17.07 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 5 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 54.479 cm^3/mol📊 OPERA
Polarizability 21.597 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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