Cacao absolute (CAS 8002-31-1) — Sweet Base Note Fragrance Ingredient

Sweet · Balsamic

Cacao absolute

CAS 8002-31-1

Origin
natural
Note
Base
IFRA
Generally safe
Data as of: Apr 2026

What Is Cacao absolute?

Cacao absolute is a rich, chocolatey extract derived from cocoa beans. You’ll find it in gourmand perfumes, candles, and luxury chocolates. This ingredient matters because it adds a decadent, edible quality to fragrances, evoking childhood memories and comfort foods with its deep cocoa aroma.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Contains trace theobromine – check for pet safety
CAS
8002-31-1
Formula
Mixture
MW
Variable
Odor Family
Sweet · Balsamic
Layer 1 · Enthusiast

What Does Cacao absolute Smell Like?

A velvety explosion of dark chocolate fudge, roasted coffee beans, and vanilla-infused caramel. Opens with bitter cocoa powder intensity, then unfolds into a heart of warm nuttiness (think hazelnut praline) before settling into a lingering base reminiscent of aged rum barrels. The dry-down reveals subtle leathery undertones that prevent excessive sweetness.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Black Orchid(Tom Ford, 2006)

Used as the gourmand anchor, blending with truffle accord to create an opulent, almost edible chocolate-truffle fantasy that defines modern oriental gourmands.

Angel Muse(Mugler, 2016)

The cacao-vetiver duo here creates an innovative ‘chocolate mud’ effect – earthy yet luxurious, amplifying the fragrance’s gender-neutral appeal.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Cacao absolute contains over 300 volatile compounds including key methylpyrazines (chocolate odor), theobromine (bitter alkaloid), and polyphenols. The extraction process (typically solvent-based from fermented beans) concentrates fat-soluble aroma molecules while preserving the natural complexity. Unlike synthetic chocolate aromachemicals, this retains the full spectrum of roasted, fatty, and fruity nuances.

Physical & Chemical Properties

AppearanceDark brown viscous liquid
SolubilitySoluble in alcohol, fixed oils
Flash Point>100°C

Perfumer Guide

Note Position
Base
Volatility
Low (6+ hours)
Blending
Moderate – can dominate
ApplicationTypical %RangeNotes
Gourmand Perfumes0.5-2%Up to 5%Overdosing creates overwhelming foodiness
Home Fragrance1-3%Up to 8%Higher loads for olfactory impact in candles

Classic Accords

+ Vanilla + Tonka = Chocolate Truffle + Coffee + Tobacco = Smoky Mocha

Tip: Always balance with woody or spicy notes to prevent cloying sweetness.

Alternatives & Comparisons

1
Cocoa CO2 Extract CAS 84649-99-0

Cleaner profile with brighter top notes, preferred when subtle chocolate nuance is needed without gourmand dominance.

2
Ethyl Maltol CAS 4940-11-8

Synthetic alternative for caramelized sugar aspects when pure chocolate character isn’t required.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under IFRA 51st Amendment.

EU Allergen Declaration

None declared under EU Regulation No 1223/2009.

RIFM Assessment

RIFM-reviewed – safe at current usage levels in fragrance applications.

Sustainability

Sustainable sourcing concerns include rainforest deforestation for cacao plantations. Fair trade certification helps ensure ethical labor practices. The solvent extraction process has higher environmental impact than CO2 methods but yields superior olfactive results.

Explore Cacao absolute

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References

  1. Aprotosoaie et al. (2016). Flavor Chemistry of Cocoa and Cocoa Products. Food Chemistry. Link
  2. Counet et al. (2002). Use of Gas Chromatography-Olfactometry. Journal of Agricultural and Food Chemistry. Link

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 8002-31-1
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

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