Ethyl linalool (CAS 10339-55-6) — Floral Top Note Fragrance Ingredient

Floral

Ethyl linalool

CAS 10339-55-6

Origin
Synthetic
Note
Top
IFRA
Generally safe
Data as of: Mar 2026

What Is Ethyl linalool?

Ethyl linalool is a floral-scented synthetic ingredient used in perfumes and personal care products. It adds a fresh, slightly citrusy floral character to fragrances. This molecule matters because it offers perfumers a more stable alternative to natural linalool, with similar pleasant floral notes but greater longevity in formulations.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
IFRA approved for fragrance use
Potential mild skin sensitivity
CAS
10339-55-6
Formula
Mixture
MW
Variable
Odor Family
Floral
Layer 1 · Enthusiast

What Does Ethyl linalool Smell Like?

Ethyl linalool opens with a bright, airy floralcy reminiscent of lily-of-the-valley and bergamot tea. As it evolves, the heart reveals a delicate citrus-tinged lavender character, softer and more diffusive than regular linalool. The dry-down carries a whisper of sweet woodiness, like the faint memory of a spring garden after rain. Its synthetic nature gives it a cleaner, more linear progression than natural linalool sources.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Chance Eau Tendre(Chanel, 2010)

Used here to create the sparkling floralcy that defines this fragrance, blending with quince and jasmine for a dewy, youthful effect.

Light Blue(Dolce & Gabbana, 2001)

Provides the crisp floral lift to the citrus opening, acting as bridge between the bergamot and woody base notes.

Layer 2

2D Molecular Structure

Ethyl linalool

SMILES: CC\C(C)=C\CCC(C)(O)C=C

Chemistry, Properties & Perfumer Guide

The Chemistry

Ethyl linalool is a monoterpenoid alcohol derivative where the hydroxyl group of linalool is replaced with an ethoxy group. This modification increases stability while maintaining similar olfactory properties. Synthesized via ethoxylation of linalool under controlled conditions, it offers perfumers a more persistent floral note than its natural counterpart. The ethyl group slightly alters the molecule’s polarity and volatility profile.

Physical & Chemical Properties

AppearanceColorless liquid
Odor StrengthMedium

Perfumer Guide

Note Position
Top
Volatility
Medium (1-2 hours)
Blending
Very good
ApplicationTypical %RangeNotes
Fine Fragrance2-5%Up to 10%Floral modifier
Soap0.5-2%Up to 3%Stable floral note

Classic Accords

+ Citronellol = Enhanced floralcy + Hedione = Airy floral bouquet

Tip: Use to extend the freshness of citrus top notes while adding floral depth.

Alternatives & Comparisons

1
Linalool CAS 78-70-6

Natural version with more complex evolution but less stability in formulations.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. IFRA, REACH, EU Cosmetics Regulation standards update periodically. Consult current IFRA Standards Library before formulating. Not legal or regulatory advice.

IFRA Status

No restrictions under current IFRA standards.

RIFM Assessment

Considered safe for current fragrance use levels by RIFM.

Sustainability

As a synthetic material, ethyl linalool offers consistent quality without natural sourcing constraints. Its production avoids seasonal variability and potential overharvesting issues associated with natural linalool sources like lavender.

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References

  1. Bauer et al. (2001). Common Fragrance and Flavor Materials. Wiley-VCH.

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Mar 2026.

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Ingredient Data Sheet

CAS 10339-55-6

Physical Properties

Molecular Weight168.28 g/mol🔬 PubChem
LogP (Octanol-Water)3.2🔬 PubChem
Boiling Point220 °C🔬 EPA CompTox
Vapor Pressure0.135 mmHg @ 25°C📊 OPERA
Flash Point87 °C🔬 EPA CompTox
Involatility Index0.0112💻 Calculated
log Kp (skin permeability)-1.455💻 Calculated
SMILESCCC(=CCCC(C)(C=C)O)C🔬 PubChem

Volatility & Performance

Fragrance NoteHeart💻 Calculated
Volatility ClassSlow💻 Calculated
Persistence Score1.6 / 5💻 Calculated

Odor & Flavor

Primary Descriptorsfloral• leffingwell
Functional Groupsalcoholalkene💻 RDKit
“3.7-Dimethyl-1,6-nonadien-3-ol, This alcohol has been suggested for use in NOTE:The name ““EthylIinalo;l - is somewhat perfume compositions as a modifier for Lina- misleading in that the material is only one Iool with certain advantages over that mare- Carbon higher homologue than Linalool. Along with Ethyl Iinalyl acetate, it forms a pleasant Bergamot-tyFe background note even in soap perfumes, a”📖 Arctander

Regulatory Status

EU Annex IIIListed (restricted)⚖️ IFRA 51
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID9047415

Physical Properties

Molecular Weight 168.28 g/mol🔬 EPA CompTox
Density 0.862 g/cm^3🔬 EPA CTX
Boiling Point 226.496 °C📊 OPERA
Melting Point 1.94 °C📊 OPERA
Flash Point 87 °C🔬 EPA CTX
Refractive Index 1.464 Dimensionless📊 OPERA
Molar Volume 196.173 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 3.3 Log10 unitless🔬 EPA CTX
LogD (pH 5.5) 3.45 Log10 unitless📊 OPERA
LogD (pH 7.4) 3.45 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 7.57 Log10 unitless📊 OPERA
Water Solubility 0.004 mol/L🔬 EPA CTX
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.135 mmHg🔬 EPA CTX
Viscosity 4.683 cP📊 OPERA
Surface Tension 27.231 dyn/cm📊 OPERA
Thermal Conductivity 136.614 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 20.23 Ų💻 Computed
H-Bond Donors 1 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 5 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 54.137 cm^3/mol📊 OPERA
Polarizability 21.462 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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