Labdanum, ext., Et esters (CAS 73138-66-6) — Woody Base Note Fragrance Ingredient

Woody · Balsamic

Labdanum, ext., Et esters

CAS 73138-66-6

Origin
synthetic
Note
Base
IFRA
Generally safe
Data as of: Apr 2026

What Is Labdanum, ext., Et esters?

Labdanum absolute is a rich, resinous material derived from the rockrose plant. It’s found in amber-themed perfumes and oriental fragrances. This prized ingredient has been used since ancient times for its warm, leathery-woody character. Modern perfumery values labdanum for its ability to add depth and longevity to compositions while blending seamlessly with both synthetic and natural materials.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
No significant restrictions
Possible skin sensitization at high concentrations
CAS
73138-66-6
Formula
Mixture
MW
Variable
Odor Family
Woody · Balsamic
Layer 1 · Enthusiast

What Does Labdanum, ext., Et esters Smell Like?

Labdanum absolute opens with an intense, animalic leather note reminiscent of sun-warmed saddles and medieval apothecaries. As it evolves, the resinous heart reveals complex facets: sticky amber sap, dry tobacco leaves, and a whisper of church incense. The dry-down is a masterclass in persistence – leaving a warm, musky trail that clings to skin like ancient parchment infused with honeyed woods.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Ambre Sultan(Serge Lutens, 2000)

Labdanum forms the resinous backbone of this iconic amber, blending with myrrh and coriander to create a medieval apothecary effect.

Jicky(Guerlain, 1889)

One of the first modern uses of labdanum, providing leathery depth to this groundbreaking citrus-aromatic fougère.

Chypre(Coty, 1917)

Labdanum’s resinous quality helps bridge the gap between bergamot top notes and oakmoss base in this genre-defining chypre.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Labdanum absolute contains over 300 identified compounds, primarily labdane-type diterpenes like labdanolic acid. The extraction process (typically solvent extraction of the crude resin) concentrates these heavy molecules, which are responsible for its exceptional tenacity. Key odorants include ambroxan precursors that develop during aging, contributing to the material’s legendary aging potential in perfumery.

Physical & Chemical Properties

AppearanceViscous dark brown liquid
SolubilitySoluble in alcohol, insoluble in water

Perfumer Guide

Note Position
Base
Volatility
Very low (24+ hours)
Blending
Excellent
ApplicationTypical %RangeNotes
Fine Fragrance1-3%Up to 5%Amber bases, oriental accords
Home Fragrance0.5-2%Up to 3%Adds warmth to candles/diffusers

Classic Accords

Tip: Use labdanum to ‘glue’ together disparate elements in oriental compositions – it acts as both fixative and bridge.

Alternatives & Comparisons

1
Ambroxan CAS 6790-58-5

When a cleaner, more diffusive amber effect is needed without labdanum’s leathery aspects.

2
Benzyl Resin CAS 9000-72-0

For similar resinous qualities but with brighter, more balsamic character.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under current IFRA standards.

EU Allergen Declaration

None specified in EU Cosmetics Regulation No 1223/2009.

RIFM Assessment

RIFM assessment confirms safe use at current industry levels.

Sustainability

Wild-harvested in Mediterranean regions, labdanum collection supports rural economies but requires sustainable practices to prevent overharvesting. The labor-intensive collection process (traditionally using leather straps to gather resin from bushes) contributes to its premium price point. Recent cultivation initiatives aim to ensure long-term supply.

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References

  1. Boelens, M.H. (1995). Chemical and Sensory Evaluation of Labdanum Oil. Perfumer & Flavorist.
  2. Arctander, S. (1960). Perfume and Flavor Materials of Natural Origin.

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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