Magnesium chloride (MgCl2) (CAS 7786-30-3) — Citrus None Note Fragrance Ingredient

Citrus · Floral

Magnesium chloride (MgCl2)

CAS 7786-30-3

Origin
synthetic
Note
None
IFRA
Generally safe
Data as of: Apr 2026

What Is Magnesium chloride (MgCl2)?

Magnesium chloride is an inorganic salt primarily used in industrial applications and food processing. It’s found in de-icing agents, tofu production, and some medicinal products. While not a traditional fragrance ingredient, it occasionally appears in perfumery as a texturizing agent or stabilizer in certain formulations where its hygroscopic properties are beneficial.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
GRAS (Generally Recognized As Safe) for food use
May cause irritation in concentrated forms
CAS
7786-30-3
Formula
Mixture
MW
Variable
Odor Family
Citrus · Floral
Layer 1 · Enthusiast

What Does Magnesium chloride (MgCl2) Smell Like?

Magnesium chloride is odorless in its pure form. As an inorganic salt, it lacks the volatile organic compounds that produce scent. In perfumery applications, it serves functional rather than olfactory purposes, potentially modifying texture or acting as a carrier for other aromatic compounds without contributing its own scent profile.

Layer 2

2D Molecular Structure

Magnesium dichloride

SMILES: [Mg++].[Cl-].[Cl-]

Chemistry, Properties & Perfumer Guide

The Chemistry

Magnesium chloride is an ionic compound consisting of magnesium cations (Mg²⁺) and chloride anions (Cl⁻). It typically occurs as a hydrate in nature. Industrially produced through evaporation of seawater or brine solutions, or by reaction of magnesium hydroxide with hydrochloric acid. The hexahydrate form (MgCl₂·6H₂O) is most common. Unlike organic fragrance molecules, it doesn’t participate in scent creation but may influence product stability and texture.

Physical & Chemical Properties

Melting Point714 °C (anhydrous)
Solubility54.3 g/100 mL (20°C water)

Perfumer Guide

Note Position
None
Volatility
Non-volatile
Blending
Functional additive
ApplicationTypical %RangeNotes
Functional Additive0.1-2%Up to 5%Texture modification
Carrier Systems1-3%Up to 10%Salt-based delivery

Classic Accords

Tip: Use as a hygroscopic agent to modify product viscosity in water-based systems.

Alternatives & Comparisons

1
Sodium chloride CAS 7647-14-5

Common table salt with similar textural properties but different solubility profile.

2
Calcium chloride CAS 10043-52-4

Alternative inorganic salt with stronger hygroscopic properties for moisture control.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not restricted by IFRA – classified as non-fragrance ingredient

GHS Classification

H319 Eye irritation

RIFM Assessment

Not evaluated by RIFM as it’s not a fragrance material.

Sustainability

Magnesium chloride is abundantly available from seawater and mineral deposits. Synthetic production is energy-intensive but creates a pure product. Considered environmentally benign at typical usage levels, though mining operations can impact local ecosystems. Recycling of industrial byproducts is becoming more common.

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References

  1. PubChem Compound Summary for Magnesium chloride PubChem
  2. EFSA Panel on Food Additives (2012). Scientific Opinion on magnesium chloride. EFSA Journal. EFSA

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID5034690

Physical Properties

Molecular Weight 95.21 g/mol🔬 EPA CompTox
Density 2.313 g/cm^3🔬 EPA CTX
Boiling Point 1078.667 °C🔬 EPA CTX
Melting Point 711 °C🔬 EPA CTX

Partition & Solubility

LogP (Octanol-Water) -6.373 dimensionless💻 Computed
Water Solubility 5.313 mol/L🔬 EPA CTX

Molecular Descriptors

Topological Polar Surface Area 0 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 0 count💻 Computed
Rotatable Bonds 0 count💻 Computed
Aromatic Rings 0 count💻 Computed

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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