Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides (CAS 68424-85-1) — Green N/A Note Fragrance Ingredient

Green · Citrus

Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides

CAS 68424-85-1

Origin
synthetic
Note
N/A
IFRA
Professional use
Data as of: Apr 2026

What Is Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides?

Quaternary ammonium compounds are synthetic chemicals primarily used as disinfectants and surfactants in cleaning products. You’ll find them in household disinfectants, fabric softeners, and industrial cleaners. These compounds are valued for their antimicrobial properties, effectively killing bacteria and viruses on surfaces. Their cationic nature makes them excellent for softening fabrics and providing antistatic effects in laundry products.

Safety Profile

PROFESSIONAL USE
Generally safeUse with awarenessProfessional use
Can cause skin and eye irritation
Avoid inhalation and direct contact
CAS
68424-85-1
Formula
Mixture
MW
Variable
Odor Family
Green · Citrus
Layer 1 · Enthusiast

What Does Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides Smell Like?

Quaternary ammonium compounds typically have a faint, clean, soapy odor with subtle fatty undertones. The scent is often described as mildly antiseptic, reminiscent of hospital disinfectants. Some variants may carry a slight ammonia-like sharpness. The odor profile is generally not complex, remaining relatively static without significant top or base note evolution.

Scent Profile
Layer 2

2D Molecular Structure

C12-16-Alkylbenzyldimethylammonium chlorides

SMILES: [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 |c:18,20,t:16,lp:0:4,LN:12:1.5|

Chemistry, Properties & Perfumer Guide

The Chemistry

Quaternary ammonium compounds (QACs) are positively charged organic nitrogen compounds where the nitrogen atom is bonded to four organic groups. The benzyl-C12-16-alkyldimethyl chlorides are a class of QACs with a benzyl group and long alkyl chains (C12-16). These compounds are synthesized through the alkylation of tertiary amines with benzyl chloride. Their antimicrobial activity stems from their ability to disrupt microbial cell membranes through electrostatic interactions with negatively charged phospholipids.

Physical & Chemical Properties

AppearanceColorless to pale yellow liquid
SolubilitySoluble in water and polar organic solvents

Perfumer Guide

Note Position
N/A
Volatility
N/A
Blending
N/A
ApplicationTypical %RangeNotes
Disinfectants0.1-5%Up to 10%Effective antimicrobial concentration
Fabric Softeners3-8%Up to 15%Cationic surfactant for softening

Classic Accords

Tip: Not typically used in perfumery due to functional rather than olfactory properties.

Alternatives & Comparisons

1
Benzalkonium chloride CAS 8001-54-5

A more commonly used QAC with similar antimicrobial properties but different alkyl chain distribution.

2
Didecyldimethylammonium chloride CAS 7173-51-5

Offers broader antimicrobial spectrum with lower irritation potential in some applications.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not regulated by IFRA as it’s not used in fragrance applications.

GHS Classification

H315 Skin irritation H319 Eye irritation H335 May cause respiratory irritation

RIFM Assessment

Not evaluated by RIFM as it’s not a fragrance material.

Sustainability

QACs are persistent in the environment and can accumulate in wastewater systems. Some concerns exist about microbial resistance development. Biodegradable alternatives are being developed, but currently most commercial QACs show limited environmental degradation. Proper disposal and wastewater treatment are important considerations.

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References

  1. Zhang et al. (2015). Quaternary Ammonium Compounds (QACs). Environmental Science & Technology. DOI: 10.1021/acs.est.5b02413

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID6028492

Physical Properties

Boiling Point 325 °C📊 OPERA
Melting Point 122 °C📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 1.78 Log10 unitless📊 OPERA
LogD (pH 5.5) -0.95 Log10 unitless📊 OPERA
LogD (pH 7.4) 0.89 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 9.42 Log10 unitless📊 OPERA
Water Solubility 0 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0 mmHg📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 0 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 0 count💻 Computed
Rotatable Bonds 13 count💻 Computed
Aromatic Rings 1 count💻 Computed

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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