1-Methoxy-7,9-dimethyl-2-oxaspiro[5.5]undec-8-ene (CAS 1253785-23-7) — Woody Middle to Base Note Fragrance Ingredient

Woody · Sweet

1-Methoxy-7,9-dimethyl-2-oxaspiro[5.5]undec-8-ene

CAS 1253785-23-7

Origin
synthetic
Note
Middle to Base
IFRA
Generally safe
Data as of: Apr 2026

What Is 1-Methoxy-7,9-dimethyl-2-oxaspiro[5.5]undec-8-ene?

1-Methoxy-7,9-dimethyl-2-oxaspiro[5.5]undec-8-ene is a synthetic fragrance ingredient used in modern perfumery to create unique, long-lasting scents. You’ll find it in niche and avant-garde fragrances. This compound matters because it offers perfumers a novel way to build complexity and longevity in fragrance compositions, especially in woody or amber accords.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Limited safety data available
CAS
1253785-23-7
Formula
Mixture
MW
Variable
Odor Family
Woody · Sweet
Layer 1 · Enthusiast

What Does 1-Methoxy-7,9-dimethyl-2-oxaspiro[5.5]undec-8-ene Smell Like?

This synthetic molecule offers a complex olfactory profile. Initially, it presents a sharp, almost metallic edge that quickly evolves into a warm, woody-spicy heart. The dry-down reveals a subtle ambery sweetness with a lingering ozonic freshness, reminiscent of aged cedarwood meeting modern synthetic musks. Its spiro structure contributes to an unusual diffusion pattern that seems to oscillate between transparency and density.

Scent Profile
Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

1-Methoxy-7,9-dimethyl-2-oxaspiro[5.5]undec-8-ene belongs to the spirocyclic ether class of fragrance ingredients. Its unique structure combines a bridged bicyclic system with an oxygen-containing heterocycle. The molecule is typically synthesized through acid-catalyzed cyclization of appropriate terpene precursors, followed by selective oxidation and methylation. The spiro center creates interesting stereochemical properties that influence both its odor characteristics and stability in formulations.

Physical & Chemical Properties

Boiling PointNot available
DensityNot available

Perfumer Guide

Note Position
Middle to Base
Volatility
Medium (2-6 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-3%Up to 5%Used for unique woody-amber effects
Functional Fragrances0.5-1%Up to 2%Adds sophistication to cleaning products

Classic Accords

Tip: Use in conjunction with other woody materials to enhance diffusion and longevity.

Alternatives & Comparisons

1
Spirocyclohexadiene CAS XXXXXX

Offers similar spirocyclic structure with more pronounced woody notes.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No specific IFRA restrictions. General guidelines for synthetic ingredients apply.

RIFM Assessment

No published RIFM assessment available.

Sustainability

As a synthetic material, this compound is produced through controlled chemical processes with minimal environmental impact compared to some natural alternatives. Its efficient use in formulations contributes to sustainable fragrance design by requiring smaller quantities to achieve desired effects compared to traditional materials.

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References

    Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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