2,6-Octadienal, 3,7-dimethyl-, acid-isomerized (CAS 90480-35-6) — Citrus Top Note Fragrance Ingredient

Citrus · Green

2,6-Octadienal, 3,7-dimethyl-, acid-isomerized

CAS 90480-35-6

Origin
synthetic
Note
Top
IFRA
Use with awareness
Data as of: Apr 2026

What Is 2,6-Octadienal, 3,7-dimethyl-, acid-isomerized?

2,6-Octadienal, 3,7-dimethyl-, acid-isomerized is a synthetic fragrance ingredient used to create fresh, citrusy notes in perfumes and scented products. It’s found in air fresheners, cleaning products, and some citrus-forward fragrances. This molecule matters because it provides a cost-effective alternative to natural citrus oils while offering superior stability in formulations.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
Stable in formulations
Potential skin sensitizer
CAS
90480-35-6
Formula
Mixture
MW
Variable
Odor Family
Citrus · Green
Layer 1 · Enthusiast

What Does 2,6-Octadienal, 3,7-dimethyl-, acid-isomerized Smell Like?

This synthetic aldehyde delivers a bright, zesty citrus burst reminiscent of freshly peeled lemons with a green, slightly metallic edge. The initial sharpness evolves into a cleaner, more floral citrus character as it dries down, leaving a subtle woody-herbaceous trail. Unlike natural citrus oils, it maintains remarkable tenacity while avoiding the terpenic harshness of cheaper citrus materials.

Scent Profile
Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

2,6-Octadienal, 3,7-dimethyl-, acid-isomerized belongs to the family of unsaturated aldehydes. The acid-isomerized form creates a more stable configuration than its natural counterparts. Industrial synthesis typically involves controlled acid-catalyzed isomerization of citral or related terpenoids. The resulting molecule exhibits improved oxidative stability compared to natural citrus aldehydes while maintaining similar olfactory properties.

Physical & Chemical Properties

AppearanceColorless to pale yellow liquid
SolubilitySoluble in alcohol and oils

Perfumer Guide

Note Position
Top
Volatility
Medium (1-2 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance0.5-2%Up to 5%Citrus note enhancer
Household Products0.1-0.5%Up to 1%Freshness booster

Classic Accords

Tip: Use in citrus bases to extend longevity and prevent rapid evaporation of top notes.

Alternatives & Comparisons

1
Citral CAS 5392-40-5

Natural alternative with stronger lemon character but poorer stability.

2
Lemonile CAS 100084-96-6

More stable citrus nitrile with similar fresh character.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No specific IFRA restrictions. General aldehyde precautions apply.

GHS Classification

H315 Skin irritation

RIFM Assessment

Not currently evaluated by RIFM. Considered safe at current usage levels.

Sustainability

As a synthetic material, this ingredient reduces pressure on natural citrus oil supplies. Production typically uses petroleum-derived precursors, though some manufacturers are exploring bio-based routes. Proper handling minimizes environmental release.

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References

    Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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