2-Benzylheptanol (CAS 92368-90-6) — Floral Middle Note Fragrance Ingredient

Floral · Woody

2-Benzylheptanol

CAS 92368-90-6

Origin
synthetic
Note
Middle
IFRA
Generally safe
Data as of: Apr 2026

What Is 2-Benzylheptanol?

2-Benzylheptanol is a synthetic fragrance ingredient used in perfumes and personal care products. It contributes to floral and woody scent profiles. This ingredient helps create long-lasting fragrances by balancing volatility and enhancing other notes.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for individual sensitivity
CAS
92368-90-6
Formula
Mixture
MW
Variable
Odor Family
Floral · Woody
Layer 1 · Enthusiast

What Does 2-Benzylheptanol Smell Like?

2-Benzylheptanol offers a subtle floral character with woody undertones. It evolves from a fresh, slightly green top note to a warm, creamy heart, settling into a soft, musky base. The dry-down is smooth and persistent, making it ideal for enhancing longevity in floral and oriental compositions.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Chanel No. 5(Chanel, 1921)

Used to add a creamy, floral depth to the iconic aldehydic bouquet, enhancing its timeless elegance.

J'adore(Dior, 1999)

Contributes to the lush floral heart, blending seamlessly with ylang-ylang and rose for a radiant effect.

Layer 2

2D Molecular Structure

Benzenepropanol, .beta.-pentyl-

SMILES: CCCCCC(CO)CC1=CC=CC=C1

Chemistry, Properties & Perfumer Guide

The Chemistry

2-Benzylheptanol is a synthetic alcohol with a benzyl group attached to a heptanol chain. It is typically produced through Grignard reactions or hydrogenation of corresponding ketones. The molecule’s structure allows for good stability and moderate volatility, making it versatile in perfumery.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Middle
Volatility
Moderate (2-4 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance2-5%Up to 10%Adds floral depth
Personal Care1-3%Up to 5%Enhances creaminess

Classic Accords

+ Rose + Sandalwood = Floral Woody + Vanilla + Musk = Oriental

Tip: Use to round off sharp floral notes and add creaminess.

Alternatives & Comparisons

1
Phenethyl Alcohol CAS 60-12-8

A more floral alternative with less woody character, suitable for lighter compositions.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No IFRA restrictions currently apply.

RIFM Assessment

RIFM assessment confirms safety at current usage levels.

Sustainability

As a synthetic ingredient, 2-Benzylheptanol is produced with controlled environmental impact. Its synthesis avoids the need for natural resource extraction, making it a sustainable choice for modern perfumery.

Explore 2-Benzylheptanol

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References

  1. PubChem Compound Summary for 2-Benzylheptanol PubChem

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID20869095

Physical Properties

Molecular Weight 206.329 g/mol🔬 EPA CompTox
Density 0.941 g/cm^3🔬 EPA CTX
Boiling Point 299.8 °C🔬 EPA CTX
Melting Point 29.132 °C📊 OPERA
Flash Point 151 °C🔬 EPA CTX
Refractive Index 1.506 Dimensionless📊 OPERA
Molar Volume 219.174 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 4 Log10 unitless🔬 EPA CTX
LogD (pH 5.5) 4.1 Log10 unitless📊 OPERA
LogD (pH 7.4) 4.1 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 9.1 Log10 unitless📊 OPERA
Water Solubility 0 mol/L🔬 EPA CTX
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.064 mmHg🔬 EPA CTX
Viscosity 25.737 cP📊 OPERA
Surface Tension 35.811 dyn/cm📊 OPERA
Thermal Conductivity 145.63 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 20.23 Ų💻 Computed
H-Bond Donors 1 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 7 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 65.093 cm^3/mol📊 OPERA
Polarizability 25.805 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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