alpha-Amylcinnamyl alcohol (CAS 101-85-9) — Floral Middle Note Fragrance Ingredient

Floral · Sweet

alpha-Amylcinnamyl alcohol

CAS 101-85-9

Origin
synthetic
Note
Middle
IFRA
Generally safe
Data as of: Apr 2026

What Is alpha-Amylcinnamyl alcohol?

alpha-Amylcinnamyl alcohol is a synthetic fragrance ingredient used in perfumes and personal care products. It adds floral and balsamic notes to fragrances. This ingredient matters because it helps create long-lasting scents with a warm, slightly powdery character often found in floral bouquets.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for individual sensitivity
CAS
101-85-9
Formula
Mixture
MW
Variable
Odor Family
Floral · Sweet
Layer 1 · Enthusiast

What Does alpha-Amylcinnamyl alcohol Smell Like?

alpha-Amylcinnamyl alcohol offers a delicate floral aroma with hints of lily and balsamic undertones. It evolves from a fresh, slightly green top note to a heart of powdery sweetness, settling into a warm, subtly musky base. The dry-down is reminiscent of vintage perfumes with a comforting, slightly waxy texture.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Chanel No. 5(Chanel, 1921)

Used to enhance the floral bouquet, adding a powdery warmth that balances the aldehydes and creates a timeless elegance.

Shalimar(Guerlain, 1925)

Contributes to the oriental base, blending with vanilla and tonka bean for a creamy, slightly animalic depth.

Layer 2

2D Molecular Structure

alpha-Amylcinnamyl alcohol

SMILES: CCCCCC(CO)=CC1=CC=CC=C1

Chemistry, Properties & Perfumer Guide

The Chemistry

alpha-Amylcinnamyl alcohol is a synthetic aromatic alcohol. It is produced through the reduction of alpha-amylcinnamaldehyde. The molecule features a cinnamyl alcohol structure with an amyl side chain, which influences its volatility and olfactive properties.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Middle
Volatility
Moderate (2-4 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-5%Up to 10%Adds floral warmth
Soaps0.5-2%Up to 5%Enhances floral notes

Classic Accords

Tip: Use in floral compositions to add a powdery, vintage character.

Alternatives & Comparisons

1
Cinnamyl alcohol CAS 104-54-1

Offers a similar balsamic profile but with less powdery nuance.

2
Amylcinnamaldehyde CAS 122-40-7

Provides a more aldehydic, floral character without the alcohol’s warmth.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not restricted by IFRA.

RIFM Assessment

Assessed as safe for use in current applications.

Sustainability

Synthetic production ensures consistent quality and reduces reliance on natural resources. Manufacturing processes should follow green chemistry principles to minimize environmental impact.

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References

  1. PubChem. alpha-Amylcinnamyl alcohol. PubChem
  2. IFRA Standards Library. IFRA

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID2049393

Physical Properties

Molecular Weight 204.313 g/mol🔬 EPA CompTox
Density 0.958 g/cm^3🔬 EPA CTX
Boiling Point 306.765 °C📊 OPERA
Melting Point 39.556 °C📊 OPERA
Flash Point 155.653 °C📊 OPERA
Refractive Index 1.547 Dimensionless📊 OPERA
Molar Volume 210.25 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 4.079 Log10 unitless📊 OPERA
LogD (pH 5.5) 3.369 Log10 unitless📊 OPERA
LogD (pH 7.4) 4.019 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 8.89 Log10 unitless📊 OPERA
Water Solubility 0 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.001 mmHg📊 OPERA
Viscosity 17.093 cP📊 OPERA
Surface Tension 37.069 dyn/cm📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 20.23 Ų💻 Computed
H-Bond Donors 1 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 6 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 66.684 cm^3/mol📊 OPERA
Polarizability 26.436 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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