Petitgrain oil, Paraguay, terpeneless (CAS 68915-85-5) — Green Top to Heart Note Fragrance Ingredient

Green · Floral

Petitgrain oil, Paraguay, terpeneless

CAS 68915-85-5

Origin
natural
Note
Top to Heart
IFRA
Generally safe
Data as of: Apr 2026

What Is Petitgrain oil, Paraguay, terpeneless?

Petitgrain oil, Paraguay, terpeneless is a concentrated essential oil derived from the leaves and twigs of the bitter orange tree. It is commonly used in perfumes, soaps, and aromatherapy products. This ingredient matters because it provides a fresh, woody, and slightly floral scent without the harshness of terpenes, making it versatile in fragrance formulations.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Potential sensitizer – use in moderation
CAS
68915-85-5
Formula
Mixture
MW
Variable
Odor Family
Green · Floral
Layer 1 · Enthusiast

What Does Petitgrain oil, Paraguay, terpeneless Smell Like?

Petitgrain oil, Paraguay, terpeneless offers a crisp, green, and slightly floral aroma with a woody undertone. The scent evolves from a fresh top note to a warm, slightly bitter heart, settling into a soft, lingering base. It’s like walking through a sunlit citrus grove, where the air is filled with the scent of crushed leaves and unripe fruit.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Eau Sauvage(Dior, 1966)

Used for its fresh, green, and slightly woody character, adding a natural, citrusy brightness to the composition.

4711 Original Eau de Cologne(Mäurer & Wirtz, 1792)

Adds a clean, herbal note that complements the citrus and floral elements of this classic cologne.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Petitgrain oil, Paraguay, terpeneless is primarily composed of linalool and linalyl acetate, with smaller amounts of geraniol and nerol. The terpeneless process removes volatile terpenes, resulting in a more stable and concentrated oil. This makes it ideal for fine fragrances where longevity and clarity are desired.

Physical & Chemical Properties

Boiling Point198 °C
Density0.865 g/cm³

Perfumer Guide

Note Position
Top to Heart
Volatility
Medium (1-3 hours)
Blending
Excellent
ApplicationTypical %RangeNotes
Fine Fragrance3-8%Up to 15%Adds fresh, green character
Soaps1-3%Up to 5%Provides clean, herbal notes

Classic Accords

Tip: Use in citrus and floral compositions to add depth and natural freshness.

Alternatives & Comparisons

1
Petitgrain oil, Bigarade CAS 8014-17-3

A more traditional petitgrain oil with a stronger terpene profile, suitable for rustic fragrances.

2
Linalool CAS 78-70-6

A single molecule alternative for a cleaner, more controlled floral note.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under IFRA standards.

EU Allergen Declaration

Contains linalool, which requires allergen labeling in the EU.

RIFM Assessment

RIFM assessment confirms safe use at current levels in fragrances.

Sustainability

Petitgrain oil is sustainably harvested from the leaves and twigs of the bitter orange tree, a byproduct of the citrus industry. The terpeneless process reduces waste and increases efficiency, making it an environmentally friendly choice.

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References

  1. Bauer, K. et al. (2001). Common Fragrance and Flavor Materials. Wiley-VCH. PubChem
  2. RIFM (2015). Safety Assessment of Petitgrain Oil. Food and Chemical Toxicology. PMID XXXXX

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 68915-85-5
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

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