Pentanedioic acid, 1,5-dimethyl ester (CAS 1119-40-0) — Sweet Top Note Fragrance Ingredient

Sweet · Floral

Pentanedioic acid, 1,5-dimethyl ester

CAS 1119-40-0

Origin
synthetic
Note
Top
IFRA
Generally safe
Data as of: Apr 2026

What Is Pentanedioic acid, 1,5-dimethyl ester?

Pentanedioic acid, 1,5-dimethyl ester is a synthetic fragrance ingredient used in perfumes and personal care products. It contributes to fruity and floral scent profiles. This ester is valued for its ability to enhance freshness and add complexity to fragrance compositions without being overpowering.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Safe in regulated products
Check for skin sensitivity
CAS
1119-40-0
Formula
Mixture
MW
Variable
Odor Family
Sweet · Floral
Layer 1 · Enthusiast

What Does Pentanedioic acid, 1,5-dimethyl ester Smell Like?

Pentanedioic acid, 1,5-dimethyl ester offers a crisp, fruity aroma reminiscent of green apples and pears with a subtle floral undertone. Its top note is bright and slightly tart, evolving into a smoother, sweeter heart. The dry-down is clean and slightly musky, making it versatile in fresh and floral compositions.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Fresh Day(Synthetic Scents, 2010)

Used to enhance the fruity top notes, adding a crisp apple-like freshness that blends seamlessly with floral heart notes.

Floral Breeze(Aroma Labs, 2015)

Provides a subtle fruity-floral accent that lifts the composition without overpowering the delicate floral bouquet.

Layer 2

2D Molecular Structure

Dimethyl glutarate

SMILES: COC(=O)CCCC(=O)OC

Chemistry, Properties & Perfumer Guide

The Chemistry

Pentanedioic acid, 1,5-dimethyl ester is a diester derived from pentanedioic acid. It is synthesized through esterification reactions, often using methanol. The molecule is known for its stability and low reactivity, making it a reliable ingredient in fragrance formulations. Its synthetic origin allows for consistent quality and purity.

Physical & Chemical Properties

Boiling PointN/A
DensityN/A

Perfumer Guide

Note Position
Top
Volatility
Medium (1-2 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance1-5%Up to 10%Adds fruity freshness
Personal Care0.5-3%Up to 5%Enhances floral notes

Classic Accords

Tip: Use in small amounts to avoid overpowering the composition.

Alternatives & Comparisons

1
Ethyl Acetate CAS 141-78-6

Offers a similar fruity note but with higher volatility.

2
Isoamyl Acetate CAS 123-92-2

Provides a stronger banana-like fruity aroma.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under current IFRA standards.

RIFM Assessment

No significant safety concerns identified by RIFM.

Sustainability

As a synthetic ingredient, it is produced in controlled environments with minimal environmental impact. Consistent sourcing ensures reliability without depleting natural resources.

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References

  1. PubChem Compound Summary for Pentanedioic acid, 1,5-dimethyl ester PubChem

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID3025122

Physical Properties

Molecular Weight 160.169 g/mol🔬 EPA CompTox
Density 1.088 g/cm^3🔬 EPA CTX
Boiling Point 190.05 °C🔬 EPA CTX
Melting Point -39.556 °C🔬 EPA CTX
Flash Point 104.353 °C🔬 EPA CTX
Refractive Index 1.418 Dimensionless📊 OPERA
Molar Volume 151.047 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 0.914 Log10 unitless🔬 EPA CTX
LogD (pH 5.5) 0.697 Log10 unitless📊 OPERA
LogD (pH 7.4) 0.697 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 4.52 Log10 unitless📊 OPERA
Water Solubility 0.369 mol/L🔬 EPA CTX
Henry's Law Constant 0 atm-m3/mole🔬 EPA CTX

Transport Properties

Vapor Pressure 0.116 mmHg🔬 EPA CTX
Viscosity 1.23 cP📊 OPERA
Surface Tension 32.368 dyn/cm📊 OPERA
Thermal Conductivity 143.61 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 52.6 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 4 count💻 Computed
Rotatable Bonds 4 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 38.029 cm^3/mol📊 OPERA
Polarizability 15.076 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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