Benzoin Resinoid (CAS 9000-05-09) — Balsamic Base Note Fragrance Ingredient




Benzoin Resinoid

CAS 9000-05-09

Origin
Note
IFRA
Generally safe
Data as of: Mar 2026

What Is Benzoin Resinoid?

Benzoin resinoid is a warm, vanilla-like aromatic material derived from the bark of Styrax trees. People encounter it in incense, perfumes, and some food flavorings. This resinous material has been prized for centuries for its rich, balsamic qualities that add depth and warmth to fragrances.

Safety Profile

GENERALLY SAFE

Generally safeUse with awarenessProfessional use
Safe in regulated products
May cause skin sensitivity in some individuals
CAS
9000-05-09
Formula
Mixture
MW
Variable
Odor Family
Layer 1 · Enthusiast

What Does Benzoin Resinoid Smell Like?

Benzoin resinoid unfolds with an initial burst of sweet, powdery vanilla with hints of caramelized sugar. As it settles, the heart reveals a complex balsamic character reminiscent of aged leather and dried fruits, with subtle smoky undertones. The dry-down is warm, creamy, and slightly woody, leaving a comforting amber-like trail that persists for hours. Its aroma is like liquid gold – rich, enveloping, and slightly medicinal in the best possible way.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Shalimar(Guerlain, 1925)

Used as a balsamic fixative that blends seamlessly with vanilla and iris, creating Shalimar’s legendary oriental warmth.

Opium(Yves Saint Laurent, 1977)

Provides the resinous depth that defines this spicy oriental, complementing the myrrh and patchouli.

Ambre Sultan(Serge Lutens, 2000)

Contributes to the rich amber accord, adding sweetness and longevity to this Middle Eastern-inspired composition.

Tobacco Vanille(Tom Ford, 2007)

Enhances the vanilla-tobacco pairing with its balsamic sweetness and resinous texture.

Bois d’Arménie(Guerlain, 2006)

Forms the core of this fragrance, recreating the scent of Armenian paper with its warm, papery-resinous character.

Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Benzoin resinoid is composed primarily of benzoic acid esters (especially coniferyl benzoate) and vanillin derivatives. The resin is obtained through solvent extraction of Styrax benzoin bark exudates. The composition varies depending on the Styrax species (S. tonkinensis vs S. benzoin) and geographical origin. Key aroma compounds include cinnamic acid derivatives and phenylpropanoids that contribute to its characteristic balsamic-sweet profile.

Physical & Chemical Properties

Appearance Dark brown viscous liquid
Solubility Soluble in alcohol and fixed oils

Perfumer Guide

Note Position
Base
Volatility
Low (8+ hours)
Blending
Excellent
Application Typical % Range Notes
Fine Fragrance 1-3% Up to 5% Used as fixative in oriental compositions
Incense 5-10% Up to 15% Provides warm, resinous character
Soap/Cosmetics 0.5-1% Up to 2% Adds warmth to amber accords

Classic Accords

+ Vanilla + Tonka = Gourmand Base
+ Labdanum + Vanilla = Amber Accord
+ Patchouli + Sandalwood = Oriental Base

Tip: Use benzoin resinoid to add warmth and diffusion to vanilla-heavy compositions without making them overly sweet.

Alternatives & Comparisons

1
Peru Balsam CAS 8007-00-3

More cinnamon-like with similar balsamic properties but stronger odor impact.

2
Tolu Balsam CAS 9000-64-0

Offers comparable resinous qualities but with more floral-cinnamon nuances.

3
Vanillin CAS 121-33-5

For pure vanilla sweetness without the resinous complexity.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. IFRA, REACH, EU Cosmetics Regulation standards update periodically. Consult current IFRA Standards Library before formulating. Not legal or regulatory advice.

IFRA Status

No IFRA restrictions. Generally recognized as safe for use in fragrances.

EU Allergen Declaration

Contains benzyl benzoate which requires declaration above 0.001% in leave-on products.

RIFM Assessment

RIFM has evaluated benzoin resinoid and found it safe for current use levels in fragrances.

Sustainability

Benzoin is sustainably harvested by making careful incisions in the bark of Styrax trees, allowing resin to exude without harming the tree. The resinoid production through solvent extraction is more efficient than traditional tincturing methods. Synthetic alternatives exist but lack the full complexity of natural benzoin.

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Industry & Science Data

Commercial Price
$20–$50/kg
natural grade, bulk market
Indicative 2024 pricing. Varies by purity & volume.
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References

  1. Arctander, S. (1960). Perfume and Flavor Materials of Natural Origin.
  2. Bauer, K. et al. (2001). Common Fragrance and Flavor Materials.
  3. IFRA Standards Library IFRA

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Mar 2026.

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