N-Ethyl-N-(3-methylphenyl)propionamide (CAS 179911-08-1) — Musky Middle to base Note Fragrance Ingredient

Musky · Woody

N-Ethyl-N-(3-methylphenyl)propionamide

CAS 179911-08-1

Origin
synthetic
Note
Middle to base
IFRA
Use with awareness
Data as of: Apr 2026

What Is N-Ethyl-N-(3-methylphenyl)propionamide?

N-Ethyl-N-(3-methylphenyl)propionamide is a synthetic fragrance ingredient used in modern perfumery. It’s found in niche and designer fragrances where its unique properties enhance scent profiles. This molecule matters because it offers perfumers a novel olfactory tool, allowing creation of contemporary scent signatures that stand out in crowded markets.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
No major restrictions in current IFRA guidelines
Limited safety data – use conservative levels
CAS
179911-08-1
Formula
Mixture
MW
Variable
Odor Family
Musky · Woody
Layer 1 · Enthusiast

What Does N-Ethyl-N-(3-methylphenyl)propionamide Smell Like?

This synthetic amide presents a complex olfactory profile opening with sharp, almost metallic top notes that quickly transition to a warm, slightly animalic heart. The dry-down reveals a skin-like muskiness with subtle phenolic undertones, reminiscent of sun-warmed leather. Its evolution is linear yet sophisticated, maintaining a persistent presence without overwhelming other notes. The overall effect is intimate and modern, bridging the gap between clean synthetics and organic warmth.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Molecule 04(Escentric Molecules, 2018)

Featured as the sole note, showcasing its full spectrum from sharp opening to velvety dry-down, demonstrating how single molecules can create complex olfactory experiences.

Synthetic Jungle(Frederic Malle, 2021)

Used as a modern musk counterpart to green florals, providing depth and longevity while maintaining transparency in this futuristic floral composition.

Layer 2

2D Molecular Structure

Propanamide, N-ethyl-N-(3-methylphenyl)-

SMILES: CCN(C(=O)CC)C1=CC=CC(C)=C1

Chemistry, Properties & Perfumer Guide

The Chemistry

N-Ethyl-N-(3-methylphenyl)propionamide belongs to the aromatic amide class, synthesized through condensation reactions between substituted anilines and propionic acid derivatives. Its structure features both aromatic and aliphatic components, creating unique electronic distribution that influences its odor properties. The ethyl and methyl substituents on the nitrogen and phenyl ring respectively contribute to its moderate volatility and distinctive scent profile.

Physical & Chemical Properties

AppearanceClear to pale yellow liquid
SolubilitySoluble in alcohol, slightly soluble in water

Perfumer Guide

Note Position
Middle to base
Volatility
Moderate (2-6 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance0.5-2%Up to 5%Used as a modern musk alternative
Functional Fragrance0.1-0.5%Up to 1%Provides subtle warmth in detergents

Classic Accords

Tip: Use at 0.5-1% in base notes to add subtle animalic warmth without overpowering florals.

Alternatives & Comparisons

1
Ethylene Brassylate CAS 105-95-3

For more floral musk character with better safety profile at higher concentrations.

2
Muscenone CAS 110-41-8

When a more naturalistic musk effect is desired, though less diffusive.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not currently restricted under IFRA standards. Monitor future amendments for potential classification updates.

RIFM Assessment

Under evaluation by RIFM as of 2023. Preliminary data suggests low sensitization potential.

Sustainability

As a synthetic material, production avoids natural resource depletion. Manufacturing typically uses petrochemical feedstocks, though green chemistry approaches are being explored. Future developments may focus on bio-based synthesis routes to improve sustainability profile.

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References

  1. IFRA Standards Library (2023). 49th Amendment. IFRA Standards

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Physicochemical Properties

DTXSID: DTXSID80870147

Physical Properties

Molecular Weight 191.274 g/mol🔬 EPA CompTox
Density 0.996 g/cm^3📊 OPERA
Boiling Point 291.321 °C📊 OPERA
Melting Point 41.597 °C📊 OPERA
Flash Point 129.121 °C📊 OPERA
Refractive Index 1.536 Dimensionless📊 OPERA
Molar Volume 190.34 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 2.776 Log10 unitless📊 OPERA
LogD (pH 5.5) 2.776 Log10 unitless📊 OPERA
LogD (pH 7.4) 2.776 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 7.46 Log10 unitless📊 OPERA
Water Solubility 0.006 mol/L📊 OPERA
Henry's Law Constant 0 atm-m3/mole📊 OPERA

Transport Properties

Vapor Pressure 0.001 mmHg📊 OPERA
Viscosity 8.591 cP📊 OPERA
Surface Tension 37.61 dyn/cm📊 OPERA
Thermal Conductivity 144.502 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 20.31 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 3 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 59.32 cm^3/mol📊 OPERA
Polarizability 23.516 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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