Pyroligneous acid extract (CAS 8028-47-5) — Balsamic Base Note Fragrance Ingredient

Balsamic · Woody

Pyroligneous acid extract

CAS 8028-47-5

Origin
synthetic
Note
Base
IFRA
Use with awareness
Data as of: Apr 2026

What Is Pyroligneous acid extract?

Pyroligneous acid extract, often called wood vinegar, is a smoky byproduct of charcoal production. It’s found in barbecue sauces, liquid smoke flavorings, and some niche fragrances evoking campfires or aged spirits. This ingredient matters because it provides an authentic, complex smokiness that synthetic alternatives struggle to replicate, while also having historical uses in food preservation and traditional medicine.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
GRAS for food use in small quantities
Contains variable levels of phenolic compounds
CAS
8028-47-5
Formula
Mixture
MW
Variable
Odor Family
Balsamic · Woody
Layer 1 · Enthusiast

What Does Pyroligneous acid extract Smell Like?

A dark, brooding aroma that unfolds like a damp forest after rain. Initial sharp acetic tang gives way to deep phenolic smokiness – imagine charred oak barrels meets smoldering birch bark. The dry-down reveals surprising nuances: faint medicinal leather, fermented apples, and an almost umami-rich depth that lingers for hours on skin. Unlike single-note smoke aromachemicals, this maintains a living, evolving character.

Scent Profile
Layer 2

Chemistry, Properties & Perfumer Guide

The Chemistry

Pyroligneous acid is a complex mixture produced by destructive distillation of wood, primarily containing acetic acid (10-20%), methanol, acetone, and various phenolic compounds. The exact composition varies by wood source and pyrolysis conditions. Traditional production involves condensing smoke from charcoal kilns, while modern versions may undergo fractional distillation to standardize key components. The smoky character derives mainly from guaiacol, syringol, and their derivatives.

Physical & Chemical Properties

AppearanceDark brown liquid
Density~1.01-1.10 g/cm³
pH2-3

Perfumer Guide

Note Position
Base
Volatility
Very low (12+ hours)
Blending
Challenging
ApplicationTypical %RangeNotes
Fragrance0.1-0.5%Up to 1%Powerful smoky effect
Flavor0.01-0.1%Up to 0.3%BBQ/smoked meat profiles

Classic Accords

Tip: Pre-dilute to 1% in ethanol before blending to avoid overwhelming compositions.

Alternatives & Comparisons

1
Guaiacol CAS 90-05-1

When cleaner, more controlled smokiness is needed without the complex fermentation notes.

2
Isovalencenol CAS 68527-77-5

For modern ‘clean smoke’ effects without phenolic harshness.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not specifically restricted, but falls under general guidelines for phenolic compounds (IFRA 49).

EU Allergen Declaration

Contains natural phenols that may require declaration above certain thresholds.

GHS Classification

H290 May be corrosive to metals H314 Causes severe skin burns

RIFM Assessment

RIFM has evaluated key phenolic constituents but not the full extract matrix.

Sustainability

Considered a byproduct utilization product when sourced from responsible charcoal production. Carbon footprint depends heavily on pyrolysis efficiency and transport distances. Synthetic smoke alternatives may have lower environmental impact per odor unit.

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References

  1. Oramahi, H.A. et al. (2018). Antimicrobial activity of pyroligneous acid from durian shell. Journal of Applied Pharmaceutical Science. DOI:10.7324/JAPS.2018.81019

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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